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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Adachi, Chihaya
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Naphthalene Diimide‐Based Hydrogen‐Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applicationscitations
- 2023Artificial p–n‐like Junction Based on Pure 2D Organic–Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moietiescitations
- 2023Artificial p–n‐like Junction Based on Pure 2D Organic–Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moietiescitations
- 2022Impact of excitonic and photonic loss mechanisms on the threshold and slope efficiency of organic semiconductor laserscitations
- 2022A convenient method to estimate the glass transition temperature of small organic semiconductor materialscitations
- 2021Toward Thing-to-Thing Optical Wireless Power Transfer: Metal Halide Perovskite Transceiver as an Enablercitations
- 2020Hysteresis-less and stable perovskite solar cells with a self-assembled monolayercitations
- 2020Nanosecond-time-scale delayed fluorescence molecule for deep-blue OLEDs with small efficiency rolloffcitations
- 2017Nature of the singlet and triplet excitations mediating thermally activated delayed fluorescencecitations
- 2016<i>N</i>-channel field-effect transistors with an organic-inorganic layered perovskite semiconductorcitations
- 2016textitN -channel field-effect transistors with an organic-inorganic layered perovskite semiconductorcitations
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article
Artificial p–n‐like Junction Based on Pure 2D Organic–Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moieties
Abstract
<jats:title>Abstract</jats:title><jats:p>2D organic–inorganic perovskites are an emerging class of materials with great potential for optoelectronics since a wide variety of large functional chromophores can be regularly incorporated. Among this new type of materials, hybrid perovskite systems incorporating strong electron acceptor molecules are considered as a promising approach to designing a new type of functional 2D perovskites for optoelectronics. In this work, a rare example of organic–inorganic 2D perovskite incorporating strong acceptors such as naphthalene diimide (NDI) building blocks between inorganic sheets is presented. This hybrid architecture forms highly air‐stable thin films with a structure consisting of inorganic perovskite monolayers of metal‐halide octahedra separated by bilayers of NDI‐based organic cations. The presence of strong electron‐accepting moieties in this multifunctional donor–acceptor hybrid heterostructure leads to a rare type II heterojunction in which the excitons can be efficiently dissociated via the electron‐transfer process and in which holes and electrons can be easily confined in the inorganic and organic sublayers, respectively. Such an ultimate p–n heterojunction shows improved photoconduction properties with a photocurrent multiplied by ≈40 under white‐light illumination in comparison to a similar 2D perovskite structure containing optically and electrically inert alkyl chains as organic components.</jats:p>