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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Raja, Robert
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Using small angle neutron scattering to explore porosity, connectivity and accessibility, towards optimised hierarchical solid acid catalystscitations
- 2022New insights in establishing the structure-property relations of novel plasmonic nanostructures for clean energy applicationscitations
- 2021Rational design and application of covalent organic frameworks for solar fuel productioncitations
- 2020Combining photocatalysis and optical fibre technology towards improved microreactor design for hydrogen generation with metallic nanoparticlescitations
- 2020Incorporating metal organic frameworks within microstructured optical fibers toward scalable photoreactorscitations
- 2017Heterogeneous zeotype catalysts for the direct utilisation of CO2
- 2017The molecular design of active sites in nanoporous materials for sustainable catalysiscitations
- 2013Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architecturescitations
- 2009Designed nanoporous solids for the green production of vitamins, fine chemicals and renewable nylonscitations
Places of action
Organizations | Location | People |
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article
Incorporating metal organic frameworks within microstructured optical fibers toward scalable photoreactors
Abstract
Optical fiber technology has revolutionized the telecommunications industry, though is still under‐utilized in chemistry. Optical fibers open many avenues for introducing, and containing, light in chemical reactions, as part of a photoreactor. This work shows, for the first time, a design strategy for incorporating a photocatalytic, nanoporous framework (Co ZIF‐67) within the internal capillaries of an optical fiber, in doing so creating an all‐in‐one, plug‐in‐and‐play photoreactor. This system improves the reactivity of the photocatalyst, relative to the powdered form, for C—H activation leading to C—C bond formation, a significant process in pharmaceutical and organic synthesis. Performing this reaction using solar energy, and low temperature demonstrates the clear potential for these systems for large scale industrial applications.