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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mathevet, Fabrice
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Topics
Publications (11/11 displayed)
- 2024Naphthalene Diimide‐Based Hydrogen‐Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applicationscitations
- 2023Artificial p–n‐like Junction Based on Pure 2D Organic–Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moietiescitations
- 2023Artificial p–n‐like Junction Based on Pure 2D Organic–Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moietiescitations
- 2022D-π-A-Type Pyrazolo[1,5-a]pyrimidine-Based Hole-Transporting Materials for Perovskite Solar Cells: Effect of the Functionalization Positioncitations
- 2018Strong Nonlinear Optical Response in the Visible Spectral Range with Epsilon‐Near‐Zero Organic Thin Filmscitations
- 2016<i>N</i>-channel field-effect transistors with an organic-inorganic layered perovskite semiconductorcitations
- 2016Chemical engineering of donor–acceptor liquid crystalline dyads and triads for the controlled nanostructuration of organic semiconductorscitations
- 2016textitN -channel field-effect transistors with an organic-inorganic layered perovskite semiconductorcitations
- 2012Influence of polymorphism on charge transport properties in isomers of fluorenone-based liquid crystalline semiconductorscitations
- 2011Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayerscitations
- 2010Diethynylbenzene-Based Liquid Crystalline Semiconductor for Solution-Processable Organic Thin-Film Transistorscitations
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article
Strong Nonlinear Optical Response in the Visible Spectral Range with Epsilon‐Near‐Zero Organic Thin Films
Abstract
<jats:title>Abstract</jats:title><jats:p>Enhanced Kerr nonlinearities are observed in metamaterials such as conducting oxides and doped inorganic semiconductor thin films showing epsilon‐near‐zero (ENZ) response in the infrared region. However, to achieve ENZ in the visible, artificial metamaterials with more complex nanostructures have to be specifically designed. Here, using sodium [5,6‐dichloro‐2‐[[5,6‐dichloro‐1‐ethyl‐3‐(4‐sulphobutyl)‐benzimidazol‐2‐ylidene]‐propenyl]‐1‐ethyl‐3‐(4‐sulphobutyl)‐benzimidazolium hydroxide] and [2,4‐bis[8‐hydroxy‐1,1,7,7‐tetramethyljulolidin‐9‐yl]squaraine] organic thin films, ENZ responses between 450 and 620 nm are demonstrated. Both nonlinear refractive index and nonlinear absorption coefficient are enhanced by more than two orders of magnitude in the ENZ spectral region. These optical effects in the visible spectral range come from the strongly dispersive permittivity of molecular aggregates resulting from the coupling of excitonic transition dipoles. These findings open the path toward a next generation of high‐performance solution‐processable organic nonlinear optical materials with ENZ properties that can be tuned by molecular engineering.</jats:p>