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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wojciechowski, Konrad
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Topics
Publications (9/9 displayed)
- 2022Modification of a Buried Interface with Bulky Organic Cations for Highly Stable Flexible Perovskite Solar Cellscitations
- 2022Inkjet Printing of Quasi‐2D Perovskite Layers with Optimized Drying Protocol for Efficient Solar Cellscitations
- 2022Solution-processable perylene diimide-based electron transport materials as non-fullerene alternatives for inverted perovskite solar cellscitations
- 2022Solution-processable perylene diimide-based electron transport materials as non-fullerene alternatives for inverted perovskite solar cellscitations
- 2021Designing New Indene-Fullerene Derivatives as Electron-Transporting Materials for Flexible Perovskite Solar Cellscitations
- 2015Templated microstructural growth of perovskite thin films via colloidal monolayer lithographycitations
- 2015Phosphonic anchoring groups in organic dyes for solid-state solar cellscitations
- 2015Phosphonic anchoring groups in organic dyes for solid-state solar cellscitations
- 2015Highly efficient, flexible, indium-free perovskite solar cells employing metallic substratescitations
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article
Inkjet Printing of Quasi‐2D Perovskite Layers with Optimized Drying Protocol for Efficient Solar Cells
Abstract
<jats:title>Abstract</jats:title><jats:p>Metal halide perovskites of reduced dimensionality constitute an interesting subcategory of the perovskite semiconductor family, which attract a lot of attention, primarily due to their excellent moisture resistance and peculiar optoelectronic properties. Specifically, quasi‐2D materials of the Ruddlesden–Popper (RP) type, are intensely investigated as photoactive layers in perovskite solar cells. Here, a scalable deposition of quasi‐2D perovskite thin films, with a nominal composition of 4F‐PEA<jats:sub>2</jats:sub>MA<jats:sub>4</jats:sub>Pb<jats:sub>5</jats:sub>I<jats:sub>16</jats:sub> (4‐FPEA<jats:sup>+</jats:sup>‐4‐fluoro‐phenethylammonium, applied as a spacer cation), using an inkjet printing technique, is developed. An optimized precursor formulation, and appropriate post‐printing treatment, which enable good control over nucleation and crystal growth steps, result in highly crystalline and uniform perovskite layers. Particularly, vacuum with nitrogen flushing provides an optimal drying treatment, which produces a more uniform distribution of low dimensional phases, and a high level of vertical (out‐of‐plane) alignment, which is beneficial for charge carrier transport. Solar cells reaching 13% of power conversion efficiency for the rigid, and 10.6% for the flexible, large area (1 cm<jats:sup>2</jats:sup>) devices are presented.</jats:p>