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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schmidt, Christina
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Topics
Publications (8/8 displayed)
- 2024Tunable LiZn‐Intermetallic Coating Thickness on Lithium Metal and Its Effect on Morphology and Performance in Lithium Metal Batteriescitations
- 2023Role of Fe/Co Ratio in Dual Phase Ce0.8Gd0.2O2−δ–Fe3−xCoxO4 Composites for Oxygen Separationcitations
- 2023Emission ratio determination from road vehicles using a range of remote emission sensing techniquescitations
- 2023Large-scale automated emission measurement of individual vehicles with point samplingcitations
- 2023Water-mediated synthesis of halide solid electrolyte and conducting polymer hybrid materials for all solid-state batteriescitations
- 2022Venetoclax synergizes with gilteritinib in FLT3 wild-type high-risk acute myeloid leukemia by suppressing MCL-1citations
- 2021Measurement of polarization effects in dual-phase ceria-based oxygen permeation membranes using Kelvin probe force microscopycitations
- 2016Threedimensional phasefield investigation of pore space cementation and permeability in quartz sandstone
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article
Tunable LiZn‐Intermetallic Coating Thickness on Lithium Metal and Its Effect on Morphology and Performance in Lithium Metal Batteries
Abstract
Lithium metal batteries are promising next‐generation rechargeable batteries with high energy density. However, the high reactivity of lithium metal leads to an undesirable growth of high surface area lithium during electrodeposition and ‐dissolution and remains a key challenge that must be addressed to enable commercialization. Modification of the Li metal surface to obtain protective coatings is a common method to overcome these challenges. In this study, the influence of the thickness of an intermetallic coating on Li metal is investigated after application by means of thermal evaporation. In addition, the relevance of pre‐treatments in reducing the native layer thickness and surface roughness by roll‐pressing Li metal prior to coating is demonstrated. Morphological analyses are performed on cross‐sections prepared under cryogenic conditions to investigate the origin of high surface area lithium growth and coating cracks after electrodeposition and ‐dissolution processes. The results obtained support the conclusion that the exclusive combination of roll‐pressed Li metal foil followed by coating reduces overvoltage and improves cycle life at elevated current densities.