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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rumpel, Matthias
University of Twente
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2024Development of Components for Solid-State Batteries and their Characterization ; Entwicklung von Komponenten für Festkörperbatterien und deren Charakterisierung
- 2022Thermal stabilities of Mn-based active materials in combination with the ceramic electrolyte LATP for ASSB bulk cathodescitations
- 2022Impact of the sintering additive Li3PO4 on the sintering behaviour, microstructure and electrical properties of a ceramic LATP electrolytecitations
- 2021How interdiffusion affects the electrochemical performance of LiMn2O4 thin films on stainless steelcitations
- 2021How interdiffusion affects the electrochemical performance of LiMn 2 O 4 thin films on stainless steelcitations
- 2020Toward an All‐Ceramic Cathode–Electrolyte Interface with Low‐Temperature Pressed NASICON Li<sub>1.5</sub>Al<sub>0.5</sub>Ge<sub>1.5</sub>(PO<sub>4</sub>)<sub>3</sub> Electrolytecitations
Places of action
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article
Toward an All‐Ceramic Cathode–Electrolyte Interface with Low‐Temperature Pressed NASICON Li<sub>1.5</sub>Al<sub>0.5</sub>Ge<sub>1.5</sub>(PO<sub>4</sub>)<sub>3</sub> Electrolyte
Abstract
<jats:title>Abstract</jats:title><jats:p>This work shows, for the first time, the critical influence of pressure during the hot sintering stage on the ionic conductivity of the lithium super ionic conductor Li<jats:sub>1.5</jats:sub>Al<jats:sub>0.5</jats:sub>Ge<jats:sub>1.5</jats:sub>(PO<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub>. A hot press method is developed to obtain high ionic conductivities at the significantly decreased densification temperature of only 650 °C by applying pressure (56 MPa). Considering the possible initiation of undesirable decomposition reactions when cathode materials are annealed at high temperature (typically ≥700 °C), the use of high pressure at 650 °C can significantly limit the formation of degradation by‐products. This study determines the criteria required to optimize the pressure and temperature parameters for enhancing the total ionic conductivity. Finally, this study reports an all solid‐state battery based on a LiFePO<jats:sub>4</jats:sub> olivine cathode prepared at 650 °C showing very good Li‐intercalation/deintercalation performance. Good ionic interfacial contact is achieved without using polymer and liquid electrolyte.</jats:p>