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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Istrate, Oana
Queen's University Belfast
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2019Quantification of gas permeability of epoxy resin composites with graphene nanoplateletscitations
- 2018Graphene/Polyamide Laminates for Supercritical CO2 and H2S Barrier Applications: An Approach toward Permeation Shutdowncitations
- 2018Graphene/Polyamide Laminates for Supercritical CO2 and H2S Barrier Applications: An Approach Towards Permeation Shutdowncitations
- 2014Reinforcement in melt-processed polymer-graphene composites at extremely low graphene loading levelcitations
- 2012Structure-property relationships of polymer blend/clay nanocompositescitations
- 2012The effect of maleic anhydride grafting efficiency on the flexural properties of polyethylene compositescitations
Places of action
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article
Graphene/Polyamide Laminates for Supercritical CO2 and H2S Barrier Applications: An Approach toward Permeation Shutdown
Abstract
<p>Graphene is potentially the perfect barrier material, being impermeable even to the smallest gas molecules, but in practice it is difficult to achieve defect-free graphene layers at large scale. Here, exceptional barrier performance for laminates comprising graphene nanoplatelet (GNP) paper sandwiched between two discs of polyamide 11 (PA11) is demonstrated. Results are compared with sandwich structures incorporating melt-processed GNP/PA11 composites, and with chemical vapor deposition (CVD) monolayer graphene transferred onto PA11. PA11 is of interest as a polymer commonly utilized within the oil and gas industry for antiwear and barrier layers in flexible risers. Permeation studies were undertaken for a feed mixture of carbon dioxide (CO<sub>2</sub>) with 1.48% hydrogen sulfide (H<sub>2</sub>S) at a temperature of 60 °C and pressures up to 400 bar, providing the first data for the performance of graphene as a barrier to a supercritical fluid. Whereas a GNP/PA11 composite and a CVD graphene monolayer have little effect on permeability, compared to a pure PA11 control sample, a GNP/PA11 laminate reduces CO<sub>2</sub> permeability by more than an order of magnitude, and reduces H<sub>2</sub>S permeability to an undetectable level.</p>