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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gogotsi, Yury
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (30/30 displayed)
- 2024Soft, Multifunctional MXene-Coated Fiber Microelectrodes for Biointerfacingcitations
- 2024Violation of the Wiedemann–Franz Law and Ultralow Thermal Conductivity of Ti3C2Tx MXenecitations
- 2023Correlating electronic properties with M-site composition in solid solution Ti_y_Nb_2-y_CT_x MXenescitations
- 2023Ultrastrong Ionotronic Films Showing Electrochemical Osmotic Actuationcitations
- 2023MXene Functionalized Kevlar Yarn via Automated, Continuous Dip Coatingcitations
- 2021Solution‐Processed Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i> MXene Antennas for Radio‐Frequency Communicationcitations
- 2020Rational Design of Titanium Carbide MXene Electrode Architectures for Hybrid Capacitive Deionizationcitations
- 2020Conductivity extraction of thin Ti3C2T<i>x</i> MXene films over 1–10 GHz using capacitively coupled test-fixturecitations
- 2020Bulk and Surface Chemistry of the Niobium MAX and MXene Phases from Multinuclear Solid-State NMR Spectroscopy.
- 2019The future of layer-by-layer assembly: A tribute to ACS Nano associate editor Helmuth Möhwaldcitations
- 2018Cold Sintered Ceramic Nanocomposites of 2D MXene and Zinc Oxidecitations
- 2018Stamping of Flexible, Coplanar Micro-Supercapacitors Using MXene Inkscitations
- 2018All Pseudocapacitive MXene-RuO2 Asymmetric Supercapacitorscitations
- 2017Atomic Layer Deposition of SnO2 on MXene for Li-Ion Battery Anodescitations
- 2017Engineering Ultrathin Polyaniline in Micro/Mesoporous Carbon Supercapacitor Electrodes Using Oxidative Chemical Vapor Depositioncitations
- 2017Thermoelectric Properties of Two-Dimensional Molybdenum-based MXenescitations
- 2016Ion-Exchange and Cation Solvation Reactions in Ti3C2 MXenecitations
- 2016Capacitance of two-dimensional titanium carbide (MXene) and MXene/carbon nanotube composites in organic electrolytescitations
- 2016Capacitance of two-dimensional titanium carbide (MXene) and MXene/carbon nanotube composites in organic electrolytescitations
- 2016Pseudocapacitance and excellent cyclability of 2,5-dimethoxy-1,4-benzoquinone on graphenecitations
- 2015Graphene-like carbide derived carbon for high-power supercapacitorscitations
- 2014Graphene-like carbide derived carbon for high-power supercapacitorscitations
- 2010Ultrahigh-power micrometre-sized supercapacitors based on onion-like carboncitations
- 2010Ultrahigh-power micrometre-sized supercapacitors based on onion-like carboncitations
- 2010Recent advances in understanding the capacitive storage in microporous carbonscitations
- 2008Materials for electrochemical capacitorscitations
- 2006In Situ Raman Spectroscopy Study of Oxidation of Double- andSingle-Wall Carbon Nanotubescitations
- 2006Filling carbon nanopipes with functional nanoparticles
- 2006In Situ Raman Spectroscopy Study of Oxidation of Double- and Single-Wall Carbon Nanotubescitations
- 2005Oxidation behaviour of an aluminium nitride-hafnium diboride ceramic composite
Places of action
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article
Engineering Ultrathin Polyaniline in Micro/Mesoporous Carbon Supercapacitor Electrodes Using Oxidative Chemical Vapor Deposition
Abstract
<jats:p>In this work, oxidative chemical vapor deposition (oCVD) is demonstrated to enable the integration of nanometer‐thin polyaniline (PANI) that significantly improves charge storage capacity of supercapacitors utilizing carbide‐derived carbon (CDC) with a bimodal (micro/mesoporous) pore size distribution. To our knowledge, this work is the first reported synthesis of PANI via oCVD. The oCVD process allows for the integration of PANI into pores as small as 1.7 nm, and resulting CDC/PANI electrodes have a gravimetric capacitance more than twice that of bare CDC (136 F g<jats:sup>−1</jats:sup> for 11 wt% of PANI in the CDC electrode versus 60 F g<jats:sup>−1</jats:sup> for bare Mo<jats:sub>2</jats:sub>C‐CDC at 10 mV s<jats:sup>−1</jats:sup>). This yields a PANI‐only gravimetric capacitance of ≈690 F g<jats:sup>−1</jats:sup>, which is close to the theoretical value of 750 F g<jats:sup>−1</jats:sup>. The coating preserves the native electrode surface area and pore size distribution, while improving capacitance due to the faradaic redox reactions of PANI. Even at high scan rates of over 100 mV s<jats:sup>−1</jats:sup>, the added pseudocapacitance from PANI remains evident. The composite electrode exhibits good cyclability, decreasing to 90% of the initial value (≈100 F g<jats:sup>−1</jats:sup>) after 10 000 cycles.</jats:p>