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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tamura, Nobumichi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Local strain inhomogeneities during electrical triggering of a metal–insulator transition revealed by X-ray microscopycitations
- 2024An Integrated Deposition and Passivation Strategy for Controlled Crystallization of 2D/3D Halide Perovskite Filmscitations
- 2022Reactive binder and aggregate interfacial zones in the mortar of Tomb of Caecilia Metella concrete, 1C BCE, Romecitations
- 2021Out-of-equilibrium processes in crystallization of organic-inorganic perovskites during spin coatingcitations
- 2020Resistive contribution in electrical-switching experiments with antiferromagnetscitations
- 2019Lattice Strain Causes Non-Radiative Losses in Halide Perovskitescitations
- 2018Local Strain Heterogeneity Influences the Optoelectronic Properties of Halide Perovskites
- 2017Residual stress determination in oxide layers at different length scales combining Raman spectroscopy and X-ray diffraction: Application to chromia-forming metallic alloyscitations
- 2016In-situ characterization of highly reversible phase transformation by synchrotron X-ray Laue microdiffractioncitations
- 2016Controlling the Temperature and Speed of the Phase Transition of VO<sub>2</sub> Microcrystalscitations
- 2015Complementary use of monochromatic and white-beam X-ray micro-diffraction for the investigation of ancient materialscitations
- 2006White beam microdiffraction experiments for the determination of the local plastic behaviour of polycrystalscitations
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article
An Integrated Deposition and Passivation Strategy for Controlled Crystallization of 2D/3D Halide Perovskite Films
Abstract
<jats:title>Abstract</jats:title><jats:p>This work introduces a simplified deposition procedure for multidimensional (2D/3D) perovskite thin films, integrating a phenethylammonium chloride (PEACl)‐treatment into the antisolvent step when forming the 3D perovskite. This simultaneous deposition and passivation strategy reduces the number of synthesis steps while simultaneously stabilizing the halide perovskite film and improving the photovoltaic performance of resulting solar cell devices to 20.8%. Using a combination of multimodal in situ and additional ex situ characterizations, it is demonstrated that the introduction of PEACl during the perovskite film formation slows down the crystal growth process, which leads to a larger average grain size and narrower grain size distribution, thus reducing carrier recombination at grain boundaries and improving the device's performance and stability. The data suggests that during annealing of the wet film, the PEACl diffuses to the surface of the film, forming hydrophobic (quasi‐)2D structures that protect the bulk of the perovskite film from humidity‐induced degradation.</jats:p>