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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Anaya, Miguel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Composition dictates octahedral tilt and photostability in halide perovskites
- 2024Composition dictates octahedral tilt and photostability in halide perovskitescitations
- 2024Multimodal operando microscopy reveals that interfacial chemistry and nanoscale performance disorder dictate perovskite solar cell stability
- 2024Multifold Enhanced Photon Upconversion in a Composite Annihilator System Sensitized by Perovskite Nanocrystals.
- 2023Surfactant-Dependent Bulk Scale Mechanochemical Synthesis of CsPbBr3 Nanocrystals for Plastic Scintillator-Based X-ray Imagingcitations
- 2023Surfactant-Dependent Bulk Scale Mechanochemical Synthesis of CsPbBr3 Nanocrystals for Plastic Scintillator-Based X-ray Imaging.
- 2022An open-access database and analysis tool for perovskite solar cells based on the FAIR data principlescitations
- 2022Local nanoscale phase impurities are degradation sites in halide perovskitescitations
- 2022Local nanoscale phase impurities are degradation sites in halide perovskites.
- 2022Stabilized tilted-octahedra halide perovskites inhibit local formation of performance-limiting phases.
- 2021An open-access database and analysis tool for perovskite solar cells based on the FAIR data principlescitations
- 2021Halide perovskites scintillators: unique promise and current limitations.
- 2021Unraveling the varied nature and roles of defects in hybrid halide perovskites with time-resolved photoemission electron microscopycitations
- 2021Nanoscale chemical heterogeneity dominates the optoelectronic response of alloyed perovskite solar cellscitations
- 2021Stabilized tilted-octahedra halide perovskites inhibit local formation of performance-limiting phasescitations
- 2021Unraveling the varied nature and roles of defects in hybrid halide perovskites with time-resolved photoemission electron microscopy.
- 2020Performance-limiting nanoscale trap clusters at grain junctions in halide perovskites.
- 2020Multi-source vacuum deposition of methylammonium-free perovskite solar cells
- 2019Identifying and Reducing Interfacial Losses to Enhance Color-Pure Electroluminescence in Blue-Emitting Perovskite Nanoplatelet Light-Emitting Diodes.
- 2015Highly Efficient Perovskite Solar Cells with Tunable Structural Colorcitations
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article
Composition dictates octahedral tilt and photostability in halide perovskites
Abstract
<jats:title>Abstract</jats:title><jats:p>Halide perovskites are excellent candidate materials for use in solar cell, LED, and detector devices, in part because their composition can be tuned to achieve ideal optoelectronic properties. Empirical efficiency optimisation has led the field towards compositions rich in FA (formamidinium) on the A‐site and I on the X‐site, with additional small amounts of MA (methylammonium) or Cs A‐site cations and Br X‐site anions. However, it is not clear how and why the specific compositions of alloyed, i.e., mixed component, halide perovskites relate to photo‐stability of the materials. Here, we combine synchrotron grazing incidence wide‐angle x‐ray scattering, photoluminescence, high‐resolution scanning electron diffraction measurements and theoretical modelling to reveal the links between material structure and photostability. Namely, we find that increased octahedral titling leads to improved photo‐stability that is correlated with lower densities of performance‐harming hexagonal polytype impurities. Our results uncover the structural signatures underpinning photo‐stability and can therefore be used to make targeted changes to halide perovskites, bettering the commercial prospects of technologies based on these materials.</jats:p><jats:p>This article is protected by copyright. All rights reserved</jats:p>