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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Köbler, Hans
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Topics
Publications (14/14 displayed)
- 2024How to accelerate outdoor ageing of perovskite solar cells by indoor testing
- 2024Hollow Cathode Gas Flow Sputtering of Nickel Oxide Thin Films for Hole‐Transport Layer Application in Perovskite Solar Cells
- 2023Large grain size with reduced non-radiative recombination in potassium incorporated methylammonium-free perovskite solar cellscitations
- 2023Stabilization of Inorganic Perovskite Solar Cells with a 2D Dion–Jacobson Passivating Layercitations
- 2023Stabilisation of Inorganic Perovskite Solar Cells with A 2d Dion-Jacobson Passivating Layercitations
- 2023Investigation of the operational stability of metal-halide perovskite solar cells ; Untersuchung der Stabilität von Metall-Halid Perowskit Solar-Zellen im Betrieb
- 2023Ink Design Enabling Slot‐Die Coated Perovskite Solar Cells with >22% Power Conversion Efficiency, Micro‐Modules, and 1 Year of Outdoor Performance Evaluationcitations
- 2023Hollow Cathode Gas Flow Sputtering of Nickel Oxide Thin Films for Hole‐Transport Layer Application in Perovskite Solar Cells
- 2022Enhanced Self-Assembled Monolayer Surface Coverage by ALD NiO in p-i-n Perovskite Solar Cellscitations
- 2021An open-access database and analysis tool for perovskite solar cells based on the FAIR data principlescitations
- 2021The challenge of designing accelerated indoor tests to predict the outdoor lifetime of perovskite solar cellscitations
- 2021Compositional and Interfacial Engineering Yield High-Performance and Stable p-i-n Perovskite Solar Cells and Mini-Modulescitations
- 2020Moisture-Induced Crystallographic Reorientations and Effects on Charge Carrier Extraction in Metal Halide Perovskite Solar Cellscitations
- 2020Ion Migration‐Induced Amorphization and Phase Segregation as a Degradation Mechanism in Planar Perovskite Solar Cells
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article
Stabilization of Inorganic Perovskite Solar Cells with a 2D Dion–Jacobson Passivating Layer
Abstract
<jats:title>Abstract</jats:title><jats:p>Inorganic metal halide perovskites such as CsPbI<jats:sub>3</jats:sub> are promising for high‐performance, reproducible, and robust solar cells. However, inorganic perovskites are sensitive to humidity, which causes the transformation from the black phase to the yellow δ, non‐perovskite phase. Such phase instability has been a significant challenge to long‐term operational stability. Here, a surface dimensionality reduction strategy is reported, using 2‐(4‐aminophenyl)ethylamine cation to construct a Dion–Jacobson 2D phase that covers the surface of the 3D inorganic perovskite structure. The Dion–Jacobson layer mainly grows at the grain boundaries of the perovskite, effectively passivating surface defects and providing favourable interfacial charge transfer. The resulting inorganic perovskite films exhibit excellent humidity resistance when submerged in an aqueous solution (isopropanol:water = 4:1 v/v) and exposed to a 50% humidity air atmosphere. The Dion–Jacobson 2D/3D inorganic perovskite solar cell (PSC) achieves a power conversion efficiency (PCE) of 19.5% with a <jats:italic>V</jats:italic><jats:sub>oc</jats:sub> of 1.197 eV. It retains 83% of its initial PCE after 1260 h of maximum power point tracking under 1.2 sun illumination. The work demonstrates an effective way for stabilizing efficient inorganic perovskite solar cells.</jats:p>