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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Getautis, Vytautas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Design, synthesis and theoretical simulations of novel spiroindane-based enamines as p-type semiconductors
- 2023Chloride-Based Additive Engineering for Efficient and Stable Wide-Bandgap Perovskite Solar Cellscitations
- 2023Chloride‐Based Additive Engineering for Efficient and Stable Wide‐Bandgap Perovskite Solar Cellscitations
- 2023Investigation of biphenyl enamines for applications as p-type semiconductors
- 2023Foldable Hole‐Transporting Materials for Merging Electronic States between Defective and Perfect Perovskite Sitescitations
- 2023Thermally cross-linkable fluorene-based hole transporting materials: synthesis, characterization, and application in perovskite solar cellscitations
- 2022Monolithic perovskite/silicon tandem solar cell with >29% efficiency by enhanced hole extraction
- 2022Advanced organic molecules for new generation solar cells /
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article
Foldable Hole‐Transporting Materials for Merging Electronic States between Defective and Perfect Perovskite Sites
Abstract
<jats:title>Abstract</jats:title><jats:p>Defective and perfect sites naturally exist within electronic semiconductors, and considerable efforts to reduce defects to improve the performance of electronic devices, especially in hybrid organic–inorganic perovskites (ABX<jats:sub>3</jats:sub>), are undertaken. Herein, foldable hole‐transporting materials (HTMs) are developed, and they extend the wavefunctions of A‐site cations of perovskite, which, as hybridized electronic states, link the trap states (defective site) and valence band edge (perfect site) between the naturally defective and perfect sites of the perovskite surface, finally converting the discrete trap states of the perovskite as the continuous valence band to reduce trap recombination. Tailoring the foldability of the HTMs tunes the wavefunctions between defective and perfect surface sites, allowing the power conversion efficiency of a small cell to reach 23.22% and that of a mini‐module (6.5 × 7 cm, active area = 30.24 cm<jats:sup>2</jats:sup>) to reach as high as 21.71% with a fill factor of 81%, the highest value reported for non‐spiro‐OMeTAD‐based perovskite solar modules.</jats:p>