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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ahmadian, Ali
Helmholtz-Institute Ulm
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2024Tailoring Mechanical Properties and Shear Band Propagation in ZrCu Metallic Glass Nanolaminates Through Chemical Heterogeneities and Interface Densitycitations
- 2024Tailoring Mechanical Properties and Shear Band Propagation in ZrCu Metallic Glass Nanolaminates Through Chemical Heterogeneities and Interface Densitycitations
- 2023Giant segregation transition as origin of liquid metal embrittlement in the Fe-Zn system
- 2023Interstitial Segregation has the Potential to Mitigate Liquid Metal Embrittlement in Ironcitations
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article
Interstitial Segregation has the Potential to Mitigate Liquid Metal Embrittlement in Iron
Abstract
<jats:title>Abstract</jats:title><jats:p>The embrittlement of metallic alloys by liquid metals leads to catastrophic material failure and severely impacts their structural integrity. The weakening of grain boundaries (GBs) by the ingress of liquid metal and preceding segregation in the solid are thought to promote early fracture. However, the potential of balancing between the segregation of cohesion‐enhancing interstitial solutes and embrittling elements inducing GB de‐cohesion is not understood. Here, the mechanisms of how boron segregation mitigates the detrimental effects of the prime embrittler, zinc, in a Σ5 [001] tilt GB in α‐Fe (4 at.% Al) is unveiled. Zinc forms nanoscale segregation patterns inducing structurally and compositionally complex GB states. Ab initio simulations reveal that boron hinders zinc segregation and compensates for the zinc‐induced loss in GB cohesion. The work sheds new light on how interstitial solutes intimately modify GBs, thereby opening pathways to use them as dopants for preventing disastrous material failure.</jats:p>