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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Anthopoulos, Thomas D.
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Contact‐Engineering of Self‐Aligned‐Gate Metal Oxide Transistors Processed via Electrode Self‐Delamination and Rapid Photonic Curingcitations
- 2024A novel selenophene based non-fullerene acceptor for near-infrared organic photodetectors with ultra-low dark currentcitations
- 2024Enhancing the Electrical Conductivity and Long‐Term Stability of PEDOT:PSS Electrodes through Sequential Treatment with Nitric Acid and Cesium Chloridecitations
- 2023Design and Piezoelectric Energy Harvesting Properties of a Ferroelectric Cyclophosphazene Saltcitations
- 2023Advances in Organometallic Perovskites Enabled Radiation Detection Technologies
- 2023A 19% efficient and stable organic photovoltaic device enabled by a guest nonfullerene acceptor with fibril-like morphologycitations
- 2023Neuromorphic computing based on halide perovskitescitations
- 2023Wirelessly powered large-area electronics for the Internet of Thingscitations
- 2023Understanding the Degradation of Methylenediammonium and Its Role in Phase-Stabilizing Formamidinium Lead Triiodidecitations
- 2022Efficient Piezoelectric Energy Harvesting from a Discrete Hybrid Bismuth Bromide Ferroelectric Templated by Phosphonium Cationcitations
- 2022Infrared Organic Photodetectors Employing Ultralow Bandgap Polymer and Non‐Fullerene Acceptors for Biometric Monitoringcitations
- 2022Oligoethylene Glycol Side Chains Increase Charge Generation in Organic Semiconductor Nanoparticles for Enhanced Photocatalytic Hydrogen Evolutioncitations
- 2022High‐Efficiency Perovskite–Organic Blend Light‐Emitting Diodes Featuring Self‐Assembled Monolayers as Hole‐Injecting Interlayerscitations
- 2021Amphipathic Side Chain of a Conjugated Polymer Optimizes Dopant Location toward Efficient N-Type Organic Thermoelectricscitations
- 2021Amphipathic Side Chain of a Conjugated Polymer Optimizes Dopant Location toward Efficient N-Type Organic Thermoelectricscitations
- 2021Ternary organic photodetectors based on pseudo-binaries nonfullerene-based acceptorscitations
- 2021Ruddlesden-Popper-Phase Hybrid Halide Perovskite/Small-Molecule Organic Blend Memory Transistorscitations
- 2020N-type organic thermoelectrics:demonstration of ZT > 0.3citations
- 2020Metal Halide Perovskites for High‐Energy Radiation Detectioncitations
- 2020Novel wide-bandgap non-fullerene acceptors for efficient tandem organic solar cellscitations
- 2020N-type organic thermoelectricscitations
- 2019High responsivity and response speed single-layer mixed-cation lead mixed-halide perovskite photodetectors based on nanogap electrodes manufactured on large-area rigid and flexible substratescitations
- 2019High throughput fabrication of nanoscale optoelectronic devices on large area flexible substrates using adhesion lithography
- 2018Charge Photogeneration and Recombination in Mesostructured CuSCN‐Nanowire/PC<sub>70</sub>BM Solar Cellscitations
- 2018p‐Doping of Copper(I) Thiocyanate (CuSCN) Hole‐Transport Layers for High‐Performance Transistors and Organic Solar Cellscitations
- 2018High‐Efficiency Fullerene Solar Cells Enabled by a Spontaneously Formed Mesostructured CuSCN‐Nanowire Heterointerfacecitations
- 2017Deep ultraviolet copper(I) thiocyanate (CuSCN) photodetectors based on coplanar nanogap electrodes fabricated via adhesion lithographycitations
- 2016Vinylene-Linked Oligothiophene-Difluorobenzothiadiazole Copolymer for Transistor Applicationscitations
- 2015An air-stable DPP-thieno-TTF copolymer for single-material solar cell devices and field effect transistorscitations
- 2013BPTs: Thiophene-flanked benzodipyrrolidone conjugated polymers for ambipolar organic transistorscitations
- 2011Structural and Electrical Characterization of ZnO Films Grown by Spray Pyrolysis and Their Application in Thin-Film Transistorscitations
- 2008Low-voltage organic transistors based on solution processed semiconductors and self-assembled monolayer gate dielectricscitations
- 2008Solution Processed Self-Assembled Monolayer Gate Dielectrics for Low-Voltage Organic Transistorscitations
Places of action
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article
Oligoethylene Glycol Side Chains Increase Charge Generation in Organic Semiconductor Nanoparticles for Enhanced Photocatalytic Hydrogen Evolution
Abstract
<jats:title>Abstract</jats:title><jats:p>Organic semiconductor nanoparticles (NPs) composed of an electron donor/acceptor (D/A) semiconductor blend have recently emerged as an efficient class of hydrogen‐evolution photocatalysts. It is demonstrated that using conjugated polymers functionalized with (oligo)ethylene glycol side chains in NP photocatalysts can greatly enhance their H<jats:sub>2</jats:sub>‐evolution efficiency compared to their nonglycolated analogues. The strategy is broadly applicable to a range of structurally diverse conjugated polymers. Transient spectroscopic studies show that glycolation facilitates charge generation even in the absence of a D/A heterojunction, and further suppresses both geminate and nongeminate charge recombination in D/A NPs. This results in a high yield of photogenerated charges with lifetimes long enough to efficiently drive ascorbic acid oxidation, which is correlated with greatly enhanced H<jats:sub>2</jats:sub>‐evolution rates in the glycolated NPs. Glycolation increases the relative permittivity of the semiconductors and facilitates water uptake. Together, these effects may increase the high‐frequency relative permittivity inside the NPs sufficiently, to cause the observed suppression of exciton and charge recombination responsible for the high photocatalytic activities of the glycolated NPs.</jats:p>