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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vos, Dirk De
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Topics
Publications (15/15 displayed)
- 2022Choline chloride–ethylene glycol based deep-eutectic solvents as lixiviants for cobalt recovery from lithium-ion battery cathode materials: are these solvents really green in high-temperature processes?citations
- 2021Porosimetry for Thin Films of Metal–Organic Frameworkscitations
- 2020Solvent-Free Powder Synthesis and Thin Film Chemical Vapor Deposition of a Zinc Bipyridyl-Triazolate Frameworkcitations
- 2017Gel-based morphological design of zirconium metal-organic frameworkscitations
- 2015Catalytic and Physicochemical Polymer Processing in Ionic Liquids
- 2014Value-added products through electrochemical CO2 fixation and decarboxylation
- 2013Dehydrochlorination of poly(vinyl chloride) and chlorinated polyethylene by phosphonium ionic liquids
- 2013High pressure, high temperature synthesis of metal-organic frameworks
- 2013Electrochemical dicarboxylation of conjugated fatty acids as an efficient valorization of carbon dioxidecitations
- 2012Electrochemical fixation of carbon dioxide in conjugated dienes: synthesis of valuable carboxylic acids
- 2011Cellulose Valorization in Ionic Liquids
- 2010Redoxreacties in ionische vloeistoffen gekoppeld aan productafscheiding
- 2009Optimization of the ionic liquid composition for the palladium-catalyzed hydrogenolysis of aromatic ketones
- 2008Catalytic reductions in ionic liquids
- 2008Catalytic Hydrogenolysis of Aromatic Ketones in Mixed Choline–Betainium Ionic Liquidscitations
Places of action
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article
Porosimetry for Thin Films of Metal–Organic Frameworks
Abstract
<p>Thin films of crystalline and porous metal–organic frameworks (MOFs) have great potential in membranes, sensors, and microelectronic chips. While the morphology and crystallinity of MOF films can be evaluated using widely available techniques, characterizing their pore size, pore volume, and specific surface area is challenging due to the low amount of material and substrate effects. Positron annihilation lifetime spectroscopy (PALS) is introduced as a powerful method to obtain pore size information and depth profiling in MOF films. The complementarity of this approach to established physisorption-based methods such as quartz crystal microbalance (QCM) gravimetry, ellipsometric porosimetry (EP), and Kr physisorption (KrP) is illustrated. This comprehensive discussion on MOF thin film porosimetry is supported by experimental data for thin films of ZIF-8.</p>