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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Thommes, Matthias
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Development and application of a novel model based on percolation theory for advanced pore network characterization by physical adsorption
- 2024Catalyst Supraparticles: Tuning the Structure of Spray‐Dried Pt/SiO2 Supraparticles via Salt‐Based Colloidal Manipulation to Control their Catalytic Performancecitations
- 2023Poly(ethylene oxide)-block-poly(hexyl acrylate) Copolymers as Templates for Large Mesopore Sizes─A Detailed Porosity Analysiscitations
- 2023Substituting fossil-based with bio-based chemicals: the case of limonene as a greener pore expander for micellar templated silicacitations
- 2022Spray‐Drying and Atomic Layer Deposition: Complementary Tools toward Fully Orthogonal Control of Bulk Composition and Surface Identity of Multifunctional Supraparticlescitations
- 2021Characterization of Hierarchically Ordered Porous Materials by Physisorption and Mercury Porosimetry—A Tutorial Reviewcitations
- 2021Porosimetry for Thin Films of Metal–Organic Frameworkscitations
- 2019Characterization and adsorption-based applications of nanoporous materials
- 2017Development of Intracrystalline Mesoporosity in Zeolites through Surfactant-Templatingcitations
- 2017Recent advances in the textural characterization of hierarchically structured nanoporous materialscitations
- 2012Mapping the location of grafted PNIPAAM in mesoporous SBA-15 silica using gas adsorption analysis.citations
- 2012Mapping the location of grafted PNIPAAM in mesoporous SBA-15 silica using gas adsorption analysiscitations
Places of action
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article
Porosimetry for Thin Films of Metal–Organic Frameworks
Abstract
<p>Thin films of crystalline and porous metal–organic frameworks (MOFs) have great potential in membranes, sensors, and microelectronic chips. While the morphology and crystallinity of MOF films can be evaluated using widely available techniques, characterizing their pore size, pore volume, and specific surface area is challenging due to the low amount of material and substrate effects. Positron annihilation lifetime spectroscopy (PALS) is introduced as a powerful method to obtain pore size information and depth profiling in MOF films. The complementarity of this approach to established physisorption-based methods such as quartz crystal microbalance (QCM) gravimetry, ellipsometric porosimetry (EP), and Kr physisorption (KrP) is illustrated. This comprehensive discussion on MOF thin film porosimetry is supported by experimental data for thin films of ZIF-8.</p>