| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Meskers, Stefan C. J.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2023Origin and Energy of Intra-Gap States in Sensitive Near-Infrared Organic Photodiodescitations
- 2023Origin and Energy of Intra-Gap States in Sensitive Near-Infrared Organic Photodiodescitations
- 2021Photo-controlled alignment and helical organization in main-chain liquid crystalline alternating polymerscitations
- 2021Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Lightcitations
- 2021Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Lightcitations
- 2021Ultralow dark current in near-infrared perovskite photodiodes by reducing charge injection and interfacial charge generationcitations
- 2020Long-lived charge-transfer state from B−N frustrated Lewis pairs enchained in supramolecular copolymerscitations
- 2020Long-lived charge-transfer state from B−N frustrated Lewis pairs enchained in supramolecular copolymerscitations
- 2020Circularly Polarized Photoluminescence from Chiral Perovskite Thin Films at Room Temperaturecitations
- 2020On the origin of dark current in organic photodiodescitations
- 2019Impact of polymorphism on the optoelectronic properties of a low-bandgap semiconducting polymercitations
- 2018The effect of oxygen on the efficiency of planar p-i-n metal halide perovskite solar cells with a PEDOT:PSS hole transport layercitations
- 2018Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in filmscitations
- 2017Thiophene rings improve the device performance of conjugated polymers in polymer solar cells with thick active layerscitations
- 2017Ultrafast charge and triplet state formation in Diketopyrrolopyrrole Low Band Gap Polymer/Fullerene blendscitations
- 2014Photoluminescence quenching in films of conjugated polymers by electrochemical dopingcitations
- 2014Effect of the fibrillar microstructure on the efficiency of high molecular weight diketopyrrolopyrrole-based polymer solar cellscitations
- 2014Relation between the electroforming voltage in alkali halide-polymer diodes and the bandgap of the alkali halidecitations
- 2012Electroforming process in metal-oxide-polymer resistive switching memories
- 2012Role of hole injection in electroforming of LiF-polymer memory diodescitations
- 2010Trapping of electrons in metal oxide-polymer memory diodes in the initial stage of electroformingcitations
- 2008Compositional and electric field dependence of the dissociation of charge transfer excitons in alternating polyfluorene copolymer/fullerene blendscitations
- 2006Synthesis and characterization of long perylenediimide polymer fibers : from bulk to the single-molecule levelcitations
- 2006Electronic memory effects in a sexithiophene - poly(ethylene oxide) block copolymer doped with NaCl. combined diode and resistive switching behaviorcitations
- 2006Triplet formation from the charge-separated state in blends of MDMO-PPV with cyano-containing acceptor polymerscitations
- 2005Exciplex dynamics in a conjugated polymer blend of MDMO-PPV and PCNEPV
- 2003Thermally induced transient absorption of light by poly(3,4-ethylenedioxythiophene):Poly(styrene sulfonic acid) (PEDOT:PSS) films: A way to probe charge-carrier thermalization processescitations
- 2002Simulation of electrical conductivity in a pi-conjugated polymeric conductor with infrared lightcitations
- 2000Relaxation of photo-excitations in films of oligo- and poly-(para-phenylene vinylene) derivativescitations
Places of action
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article
Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π-Conjugated Polymers by Light
Abstract
<p>Control over main-chain motion of chiral π-conjugated polymers can lead to unexpected new functionalities. Here, it is shown that by combining photoswitchable azobenzene units in conjugation with chiral fluorene comonomers and appropriate plasticizers, the polymer organization and chiroptical properties of these alternating copolymers steered by light and its state of polarization can be dynamically controlled. The configuration of the stereogenic centers in the side chains of the fluorene units determines the handedness of the cholesteric organization in thermally annealed films, indicating cooperative behavior. The polymer alignment and helicity of the supramolecular arrangement can be switched by irradiating with linearly and circularly polarized light, respectively. Intriguingly, when switching the handedness of thermally induced cholesteric organizations by illuminating with circularly polarized light that is opposite to the handedness of the cholesteric phases, a nematic-like intermediate state is observed during helix interconversion. By the sequence of irradiation with left and right circularly polarized light followed by thermal annealing, an asymmetric motion, reminiscent of that seen in molecular motors is observed. These findings suggest that functional conjugated polymers can exhibit emergent properties at mesoscopic scale.</p>