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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Calame, Michel
University of Basel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024AFM-IR of electrohydrodynamically printed PbS quantum dots: quantifying ligand exchange at the nanoscalecitations
- 2023On-surface synthesis and characterization of teranthene and hexanthene: ultrashort graphene nanoribbons with mixed armchair and zigzag edgescitations
- 2023Edge contacts to atomically precise graphene nanoribbonscitations
- 2022Conductive hybrid Cu-HHTP-TCNQ metal–organic frameworks for chemiresistive sensingcitations
- 2022Sensing of KCl, NaCl, and pyocyanin with a MOF-decorated electrospun nitrocellulose matrixcitations
- 2021Combining polarized Raman spectroscopy and micropillar compression to study microscale structure-property relationships in mineralized tissuescitations
- 2020Massive dirac fermion behavior in a low bandgap graphene nanoribbon near a topological phase boundarycitations
- 2020Massive Dirac Fermion Behavior in a Low Bandgap Graphene Nanoribbon Near a Topological Phase Boundary.citations
- 2020Release of graphene-related materials from epoxy-based composites: characterization, quantification and hazard assessment in vitrocitations
- 2017Multiple physical timescales and dead time rule in few-nm sized graphene-SiOx-graphene memristorscitations
- 2015Interplay between Mechanical and Electronic Degrees of Freedom in pi-Stacked Molecular Junctions: From Single Molecules to Mesoscopic Nanoparticle Networkscitations
- 2015Ordered nanoparticle arrays interconnected by molecular linkerscitations
Places of action
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article
Massive Dirac Fermion Behavior in a Low Bandgap Graphene Nanoribbon Near a Topological Phase Boundary.
Abstract
Graphene nanoribbons (GNRs) have attracted much interest due to their largely modifiable electronic properties. Manifestation of these properties requires atomically precise GNRs which can be achieved through a bottom-up synthesis approach. This has recently been applied to the synthesis of width-modulated GNRs hosting topological electronic quantum phases, with valence electronic properties that are well captured by the Su-Schrieffer-Heeger (SSH) model describing a 1D chain of interacting dimers. Here, ultralow bandgap GNRs with charge carriers behaving as massive Dirac fermions can be realized when their valence electrons represent an SSH chain close to the topological phase boundary, i.e., when the intra- and interdimer coupling become approximately equal. Such a system has been achieved via on-surface synthesis based on readily available pyrene-based precursors and the resulting GNRs are characterized by scanning probe methods. The pyrene-based GNRs (pGNRs) can be processed under ambient conditions and incorporated as the active material in a field effect transistor. A quasi-metallic transport behavior is observed at room temperature, whereas at low temperature, the pGNRs behave as quantum dots showing single-electron tunneling and Coulomb blockade. This study may enable the realization of devices based on carbon nanomaterials with exotic quantum properties.