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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Feyer, Vitaliy
Forschungszentrum Jülich
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Bi₁₂Rh₃Cu₂I₅: A 3D Weak Topological Insulator with Monolayer Spacers and Independent Transport Channelscitations
- 2024Band Structure Engineering in 2D Metal–Organic Frameworkscitations
- 2023Twist angle dependent interlayer transfer of valley polarization from excitons to free charge carriers in WSe2/MoSe2 heterobilayerscitations
- 2023Enhancing electron correlation at a 3D ferromagnetic surfacecitations
- 2023Observation of termination-dependent topological connectivity in a magnetic Weyl kagome-latticecitations
- 2023Soft X-ray Fermi surface tomography of palladium and rhodium via momentum microscopycitations
- 2023Observation of Termination-Dependent Topological Connectivity in a Magnetic Weyl Kagome Latticecitations
- 2023Observation of termination-dependent topological connectivity in a magnetic Weyl Kagome latticecitations
- 2022Bi12Rh3Cu2I5citations
- 2022Enhancing electron correlation at a 3d ferromagnetic surfacecitations
- 2021Room-temperature on-spin-switching and tuning in a porphyrin-based multifunctional interface
- 2021Room‐Temperature On‐Spin‐Switching and Tuning in a Porphyrin‐Based Multifunctional Interfacecitations
- 2019Combined orbital tomography study of multi-configurational molecular adsorbate systemscitations
- 2019Combined orbital tomography study of multi-configurational molecular adsorbate systems
- 2019Topotactic Phase Transition Driving Memristive Behaviorcitations
- 2019High-temperature 2D Fermi surface of SrTiO3 studied by energy-filtered PEEMcitations
- 2018Localized segregation of gold in ultrathin Fe films on Au(001)citations
- 2017Room temperature 2D electron gas at the (001)-SrTiO$_3$ surfacecitations
- 2015Formation and Movement of Cationic Defects During Forming and Resistive Switching in $mathrm{SrTiO_3}$ Thin Film Devicescitations
- 2015Formation and Movement of Cationic Defects During Forming and Resistive Switching in SrTiO $_{3}$ Thin Film Devicescitations
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article
Topotactic Phase Transition Driving Memristive Behavior
Abstract
Redox‐based memristive devices are one of the most attractive candidates for future nonvolatile memory applications and neuromorphic circuits, and their performance is determined by redox processes and the corresponding oxygen‐ion dynamics. In this regard, brownmillerite SrFeO2.5 has been recently introduced as a novel material platform due to its exceptional oxygen‐ion transport properties for resistive‐switching memory devices. However, the underlying redox processes that give rise to resistive switching remain poorly understood. By using X‐ray absorption spectromicroscopy, it is demonstrated that the reversible redox‐based topotactic phase transition between the insulating brownmillerite phase, SrFeO2.5, and the conductive perovskite phase, SrFeO3, gives rise to the resistive‐switching properties of SrFeOx memristive devices. Furthermore, it is found that the electric‐field‐induced phase transition spreads over a large area in (001) oriented SrFeO2.5 devices, where oxygen vacancy channels are ordered along the in‐plane direction of the device. In contrast, (111)‐grown SrFeO2.5 devices with out‐of‐plane oriented oxygen vacancy channels, reaching from the bottom to the top electrode, show a localized phase transition. These findings provide detailed insight into the resistive‐switching mechanism in SrFeOx‐based memristive devices within the framework of metal–insulator topotactic phase transitions.