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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ranc, Vaclav
in Cooperation with on an Cooperation-Score of 37%
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Publications (4/4 displayed)
- 2021Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitorscitations
- 2018Ultrathin hierarchical porous carbon nanosheets for high-performance supercapacitors and redox electrolyte energy storagecitations
- 2018Ultrathin hierarchical porous carbon nanosheets for high-performance supercapacitors and redox electrolyte energy storagecitations
- 2018Ultrathin hierarchical porous carbon nanosheets for high‐performance supercapacitors and redox electrolyte energy storagecitations
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article
Ultrathin hierarchical porous carbon nanosheets for high-performance supercapacitors and redox electrolyte energy storage
Abstract
The design of advanced high‐energy‐density supercapacitors requires the design of unique materials that combine hierarchical nanoporous structures with high surface area to facilitate ion transport and excellent electrolyte permeability. Here, shape‐controlled 2D nanoporous carbon sheets (NPSs) with graphitic wall structure through the pyrolysis of metal–organic frameworks (MOFs) are developed. As a proof‐of‐concept application, the obtained NPSs are used as the electrode material for a supercapacitor. The carbon‐sheet‐based symmetric cell shows an ultrahigh Brunauer–Emmett–Teller (BET)‐area‐normalized capacitance of 21.4 µF cm<sup>−2</sup> (233 F g<sup>−1</sup>), exceeding other carbon‐based supercapacitors. The addition of potassium iodide as redox‐active species in a sulfuric acid (supporting electrolyte) leads to the ground‐breaking enhancement in the energy density up to 90 Wh kg<sup>−1</sup>, which is higher than commercial aqueous rechargeable batteries, maintaining its superior power density. Thus, the new material provides a double profits strategy such as battery‐level energy and capacitor‐level power density.