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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hutter, Eline M.
Utrecht University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Halide Mixing in Cs2AgBi(IxBr1-x)6 Double Perovskitescitations
- 2023Conduction band tuning by controlled alloying of Fe into Cs2AgBiBr6 double perovskite powderscitations
- 2022Traps in the spotlightcitations
- 2022Traps in the spotlight: How traps affect the charge carrier dynamics in Cs2AgBiBr6 perovskite
- 2022Metal halide perovskite toxicity effects on Arabidopsis thaliana plants are caused by iodide ionscitations
- 2022Halide perovskite materials as chemical playground
- 2021Efficient vacuum deposited p-i-n and n-i-p perovskite solar cells employing doped charge transport layerscitations
- 2021Recombination and localization: Unfolding the pathways behind conductivity losses in Cs2AgBiBr6 thin films: Unfolding the pathways behind conductivity losses in Cs2AgBiBr6 thin films
- 2021Recombination and localization: Unfolding the pathways behind conductivity losses in Cs 2 AgBiBr 6 thin filmscitations
- 2021Accelerated Hot-Carrier Cooling in MAPbI3 Perovskite by Pressure-Induced Lattice Compressioncitations
- 2021Reduced Barrier for Ion Migration in Mixed-Halide Perovskitescitations
- 2021Recombination and localization: Unfolding the pathways behind conductivity losses in Cs2AgBiBr6 thin filmscitations
- 2020Charge Carrier Dynamics upon Sub-bandgap Excitation in Methylammonium Lead Iodide Thin Films: Effects of Urbach Tail, Deep Defects, and Two-Photon Absorptioncitations
- 2020Quantifying Charge-Carrier Mobilities and Recombination Rates in Metal Halide Perovskites from Time-Resolved Microwave Photoconductivity Measurementscitations
- 2020Charge Carrier Dynamics upon Sub-bandgap Excitation in Methylammonium Lead Iodide Thin Filmscitations
- 2019Comparing the calculated fermi level splitting with the open-circuit voltage in various perovskite cellscitations
- 2019Charge Carriers Are Not Affected by the Relatively Slow-Rotating Methylammonium Cations in Lead Halide Perovskite Thin Filmscitations
- 2019Charge Carriers Are Not Affected by the Relatively Slow-Rotating Methylammonium Cations in Lead Halide Perovskite Thin Films.
- 2018Maximizing and stabilizing luminescence from halide perovskites with potassium passivationcitations
- 2018Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
- 2018Band-Like Charge Transport in Cs2AgBiBr6 and Mixed Antimony-Bismuth Cs2AgBi1- xSbxBr6 Halide Double Perovskitescitations
- 2017Direct-indirect character of the bandgap in methylammonium lead iodide perovskite.
- 2017Vapour-Deposited Cesium Lead Iodide Perovskitescitations
- 2017Direct-indirect character of the bandgap in methylammonium lead iodide perovskitecitations
- 2017The Impact of Phase Retention on the Structural and Optoelectronic Properties of Metal Halide Perovskites.
- 2017Vapour-Deposited Cesium Lead Iodide Perovskites: Microsecond Charge Carrier Lifetimes and Enhanced Photovoltaic Performance.
- 2016Efficient vacuum deposited p-i-n and n-i-p perovskite solar cells employing doped charge transport layerscitations
- 2016The Impact of Phase Retention on the Structural and Optoelectronic Properties of Metal Halide Perovskitescitations
- 2016Strontium Insertion in Methylammonium Lead Iodidecitations
- 2016The Impact of Phase Retention on the Structural and Optoelectronic Properties of Metal Halide Perovskites.
- 2015Charge Carriers in Planar and Meso-Structured Organic-Inorganic Perovskitescitations
- 2015Mechanism of Charge Transfer and Recombination Dynamics in Organo Metal Halide Perovskites and Organic Electrodes, PCBM, and Spiro-OMeTADcitations
- 2015Mechanism of Charge Transfer and Recombination Dynamics in Organo Metal Halide Perovskites and Organic Electrodes, PCBM, and Spiro-OMeTAD: Role of Dark Carriers.citations
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article
The Impact of Phase Retention on the Structural and Optoelectronic Properties of Metal Halide Perovskites
Abstract
<p>Temperature-dependent X-ray diffraction (XRD) was used to study the structural changes around the low-temperature (TP?OP) phase transition of polycrystalline MAPbI<sub>3</sub> perovskite thin films prepared using a lead acetate precursor recipe on silicon substrates. Thin films of the MAPbI3 perovskite were deposited on glass, quartz or silicon substrates by spin-coating a lead acetate-based precursor solution followed by annealing of the films. The orthorhombic-to-tetragonal and vice versa phase transitions were monitored via the XRD method. The diffractograms reveal the structural evolution of the films upon a cooling/heating cycle through the TP?OP phase transition. Here, the films are controllably cooled from room temperature to 100 K and then heated back to 298 K. The diffractograms indicate clear shifts in the peak positions to higher 2θ angles upon cooling followed by a gradual shift toward lower 2θ angles during the heating cycle. Upon heating, the peak character remains OP-dominant until 160 K, when it becomes a mixed phase of both and then a predominantly TP above 170 K. These XRD results suggest that both TP and OP coexist at temperatures around the phase transition. Furthermore, the relative fraction of each phase in the temperature range of 140?160 K is not the same when comparing cooling and heating cycles, as evident from the diffractograms at 160 K.</p>