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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ahmad, Muhammad
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Strategic Fabrication of Au4Cu2 NC/ZIF-8 Composite Via In Situ Integration Technique for Enhanced Energy Storage Applicationscitations
- 2024In situ synthesis of oriented Zn-Mn-Co-telluride on precursor free CuOcitations
- 2024Synthesis and characterization of novel SEBS-g-MA/OMMT nanocomposites with thermal and mechanical resiliencecitations
- 2023Corrigendum to “Three-dimensional flower-like nanocomposites based on ZnO/NiO as effective electrode materials for supercapacitors” [J. Electroanal. Chem. 930 (2023) 117158]citations
- 2023Experimental and theoretical insights of binder-free magnesium nickel cobalt selenide star-like nanostructure as electrodecitations
- 2023Structural study of atomically precise doped Au38-xAgx NCs@ ZIF-8 electrode material for energy storage applicationcitations
- 2023In Situ Grown Heterostructure Based on MOF-Derived Carbon Containing n-Type Zn-In-S and Dry-Oxidative p-Type CuO as Pseudocapacitive Electrode Materialscitations
- 2023Understanding the Diffusion-Dominated Properties of MOF-Derived Ni–Co–Se/C on CuO Scaffold Electrode using Experimental and First Principle Studycitations
- 2023Three-dimensional flower-like nanocomposites based on ZnO/NiO as effective electrode materials for supercapacitorscitations
- 2022Fabrication of Bimetallic Cu-Ag Nanoparticle-Decorated Poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) and Its Enhanced Catalytic Activity for the Reduction of 4-Nitrophenolcitations
- 2022Comparative study of ternary metal chalcogenides (MX; M= Zn–Co–Ni; X= S, Se, Te)citations
- 2022Modified KBBF-like Material for Energy Storage Applicationscitations
- 2022Novel and Facile Synthesis of Biodegradable Plastic Films from Cornmeal by Using the Microwave Polymerization Techniquecitations
- 2022Factors affecting the growth formation of nanostructures and their impact on electrode materialscitations
- 2022Effect of growth duration of Zn0.76Co0.24S interconnected nanosheets for high-performance flexible energy storage electrode materialscitations
- 2022On-site application of solar-activated membrane (Cr–Mn-doped TiO2@graphene oxide) for the rapid degradation of toxic textile effluentscitations
- 2021An oriented Ni–Co-MOF anchored on solution-free 1D CuOcitations
- 2021Binder-free trimetallic phosphate nanosheets as an electrodecitations
- 2021Structural and Band Structure Investigation of Iron Oxide Nanoparticles Incorporated PVA Nanocomposite Filmscitations
- 2020Field electron emission measurements as a complementary technique to assess carbon nanotube qualitycitations
- 2018Physicochemical characterisation of reduced graphene oxide for conductive thin filmscitations
- 2018In Vitro Cytotoxicity and Morphological Assessments of GO-ZnO against the MCF-7 Cells: Determination of Singlet Oxygen by Chemical Trappingcitations
- 2015High Quality Carbon Nanotubes on Conductive Substrates Grown at Low Temperaturescitations
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article
Strategic Fabrication of Au4Cu2 NC/ZIF-8 Composite Via In Situ Integration Technique for Enhanced Energy Storage Applications
Abstract
Metal–organic frameworks (MOFs), known for their extensive porosity and versatile crystallinity, play a crucial role in the development of advanced energy storage materials. However, their application is limited by stability and conductivity issues. This study addresses these challenges by integrating ultrasmall metal nanoclusters, specifically Au<sub>4</sub>Cu<sub>2</sub> NC, synthesized using a mixed ligand strategy combining 2, 4-Dimethyl benzene thiol (2,4-DMBTH) and 1,2-bis(diphenylphosphino)ethane (dppe). The bimetallic Au<sub>4</sub>Cu<sub>2</sub> NC, characterized by Single Crystal X-Ray Diffraction (SCXRD), is applied to zeolitic imidazolate framework-8 (ZIF-8) using both in situ and ex situ methods to explore their electrochemical and physicochemical properties in energy storage. The in situ Au<sub>4</sub>Cu<sub>2</sub> NC/ZIF-8 composite demonstrated a specific capacitance that is almost two times higher than its ex situ counterpart, attributed to homogeneous dispersion and hence enhanced conductivity. This in situ integration of atomically precise bimetallic nanoclusters on MOFs significantly boosts supercapacitor performance, offering a more effective and reliable solution for energy storage. Further, in practical applications, this device demonstrated an energy density of 87.2 Wh kg<sup>−1</sup> at a power density of 1474 W kg<sup>−1</sup>, highlighting its robustness and potential for high-performance energy storage applications. This approach effectively combats the issue of nanocluster aggregation on substrates, marking a significant progression in supercapacitor technology. © 2024 The Author(s). Advanced Functional Materials published by Wiley-VCH GmbH.