| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Costa, Rubén D.
Technical University of Munich
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Blue‐Emitting Boron‐ and Nitrogen‐Doped Carbon Dots for White Light‐Emitting Electrochemical Cellscitations
- 2023Design Rule Hidden from The Eye in S/N‐Bridged Ancillary Ligands for Copper(I) Complexes Applied to Light‐Emitting Electrochemical Cellscitations
- 2023Cunning defects: Emission control by structural point defects on Cu(i)I double chain coordination polymerscitations
- 2023Dendri‐LEC Family: Establishing the Bright Future for Dendrimer Emitters in Traditional and Graphene‐Based Light‐Emitting Electrochemical Cellscitations
- 2022Supramolecular Chalcogen-Bonded Semiconducting Nanoribbons at Work in Lighting Devicescitations
- 2020Cunning defects: emission control by structural point defects on Cu(i)I double chain coordination polymerscitations
- 2020Meeting High Stability and Efficiency in Hybrid Light‐Emitting Diodes Based on SiO2/ZrO2 Coated CsPbBr3 Perovskite Nanocrystalscitations
- 2012Efficient blue emitting organic light emitting diodes based on fluorescent solution processable cyclic phosphazenescitations
Places of action
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article
Design Rule Hidden from The Eye in S/N‐Bridged Ancillary Ligands for Copper(I) Complexes Applied to Light‐Emitting Electrochemical Cells
Abstract
<jats:title>Abstract</jats:title><jats:p>Enhancing low‐energy emitting Cu(I)‐ionic transition metal complexes (iTMCs) light‐emitting electrochemical cells (LECs) is of utmost importance towards Cu(I)‐iTMC‐based white‐emitting LECs. Here, the ancillary ligand design includes (i) extension of π‐systems and (ii) insertion of S‐bridge between heteroaromatics rings. This led to two novel heteroleptic Cu(I)‐iTMCs: 2‐(pyridin‐2‐yl‐l2‐azanyl)quinoline (<jats:bold>CuN2</jats:bold>) and 2‐(naphthalen‐2‐ylthio)quinoline (<jats:bold>CuS2</jats:bold>) as N^N and bis[(2‐diphenylphosphino)phenyl] ether as P^P, exhibiting improved photoluminescence quantum yields (<jats:italic>ϕ</jats:italic>) and thermally activated delayed fluorescence processes compared to their reference Cu(I)‐iTMCs: di(pyridin‐2‐yl)‐l2‐azane (<jats:bold>CuN1</jats:bold>) and di(pyridin‐2‐yl)sulfane (<jats:bold>CuS1</jats:bold>). Despite <jats:bold>CuS2</jats:bold> stands out with the highest <jats:italic>ϕ</jats:italic> (38% vs 17 / 14 / 1% for <jats:bold>CuN1</jats:bold> / <jats:bold>CuN2</jats:bold> / <jats:bold>CuS1</jats:bold>), only <jats:bold>CuN2</jats:bold>‐LECs show the expected enhanced performance (0.35 cd A<jats:sup>−1</jats:sup> at luminance of 117 cd m<jats:sup>−2</jats:sup>) compared to <jats:bold>CuN1</jats:bold>‐LECs (0.02 cd A<jats:sup>−1</jats:sup> at6 cd m<jats:sup>−2</jats:sup>), while <jats:bold>CuS2</jats:bold>‐LECs feature low performances (0.04 cd A<jats:sup>−1</jats:sup> at 10 cd m<jats:sup>−2</jats:sup>). This suggests that conventional chemical design rules are not effective towards enhancing device performance. Herein, nonconventional multivariate statistical analysis and electrochemical impedance spectroscopy studies allow to rationalize the mismatch between chemical design and device performance bringing to light a hidden design rule: polarizability of the ancillary ligand is key for an efficient Cu(I)‐iTMC‐LECs. All‐in‐all, this study provides fresh insights for the design of Cu‐iTMCs fueling research on sustainable ion‐based lighting sources.</jats:p>