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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Barabash, Anastasiia
Friedrich-Alexander-Universität Erlangen-Nürnberg
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Unveiling the Role of BODIPY Dyes as Small‐Molecule Hole Transport Material in Inverted Planar Perovskite Solar Cellscitations
- 2023Enhancing Planar Inverted Perovskite Solar Cells with Innovative Dumbbell‐Shaped HTMs: A Study of Hexabenzocoronene and Pyrene‐BODIPY‐Triarylamine Derivativescitations
- 2022Highly Stable Lasing from Solution‐Epitaxially Grown Formamidinium‐Lead‐Bromide Micro‐Resonatorscitations
- 2022Shape‐Controlled Solution‐Epitaxial Perovskite Micro‐Crystal Lasers Rivaling Vapor Deposited Onescitations
- 2022Ligand Tuning of Localized Surface Plasmon Resonances in Antimony-Doped Tin Oxide Nanocrystalscitations
- 2022Laser Cutting of Metal‐Halide‐Perovskite Wafers for X‐Ray Detector Integrationcitations
- 2021Characterization of Aerosol Deposited Cesium Lead Tribromide Perovskite Films on Interdigited ITO Electrodescitations
- 2021High‐Throughput Robotic Synthesis and Photoluminescence Characterization of Aqueous Multinary Copper–Silver Indium Chalcogenide Quantum Dotscitations
Places of action
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article
Enhancing Planar Inverted Perovskite Solar Cells with Innovative Dumbbell‐Shaped HTMs: A Study of Hexabenzocoronene and Pyrene‐BODIPY‐Triarylamine Derivatives
Abstract
<jats:title>Abstract</jats:title><jats:p>Dumbbell‐shaped systems based on PAHs‐BODIPY‐triarylamine hybrids TM‐(01‐04) are designed as novel and highly efficient hole‐transporting materials for usage in planar inverted perovskite solar cells. BODIPY is employed as a bridge between the PAH units, and the effects of the conjugated <jats:italic>π</jats:italic>‐system's covalent attachment and size are investigated. Fluorescence quenching, 3D fluorescence heat maps, and theoretical studies support energy transfer within the moieties. The systems are extremely resistant to UVC 254 nm germicidal light sources and present remarkable thermal stability at degradation temperatures exceeding 350 °C. Integrating these systems into perovskite solar cells results in outstanding power conversion efficiency (PCE), with TM‐02‐based devices exhibiting a PCE of 20.26%. The devices base on TM‐01, TM‐03, and TM‐04 achieve PCE values of 16.98%, 17.58%, and 18.80%, respectively. The long‐term stability of these devices is measured for 600 h, with initial efficiency retention between 94% and 86%. The TM‐04‐based device presents noticeable stability of 94%, better than the reference polymer PTAA with 91%. These findings highlight the exciting potential of dumbbell‐shaped systems based on PAHs‐BODIPY‐triarylamine derivatives for next‐generation photovoltaics.</jats:p>