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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Guldi, Dirk M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2025Multi-material filaments for 3D printing of photoelectrocatalytic carbon nitride composites
- 2024Inverse design workflow discovers hole-transport materials tailored for perovskite solar cellscitations
- 2023Enhancing Planar Inverted Perovskite Solar Cells with Innovative Dumbbell‐Shaped HTMs: A Study of Hexabenzocoronene and Pyrene‐BODIPY‐Triarylamine Derivativescitations
- 2023Integrated System Built for Small-Molecule Semiconductors via High-Throughput Approachescitations
- 2022Highly Stable Lasing from Solution‐Epitaxially Grown Formamidinium‐Lead‐Bromide Micro‐Resonatorscitations
- 2022Shape‐Controlled Solution‐Epitaxial Perovskite Micro‐Crystal Lasers Rivaling Vapor Deposited Onescitations
- 2022Elucidating the electronic properties of single-wall carbon nanohornscitations
- 2022Exploring π-extended subporphyrinoids as electron transporting materials in perovskite solar cellscitations
- 2021Unconventional Photocatalysis in Conductive Polymers: Reversible Modulation of PEDOT:PSS Conductivity by Long‐Lived Poly(Heptazine Imide) Radicalscitations
- 2020Potassium Poly(Heptazine Imide)citations
- 2020Area‐Selective Growth of HfS <sub>2</sub> Thin Films via Atomic Layer Deposition at Low Temperaturecitations
- 2020Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenescitations
- 2020Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenescitations
- 2020Area‐Selective Growth of HfS2 Thin Films via Atomic Layer Deposition at Low Temperaturecitations
- 2015The electronic structure of Amorphous Carbon Nanodotscitations
- 2015Multistep energy and electron transfer processes in novel rotaxane donor–acceptor hybrids generating microsecond-lived charge separated statescitations
- 2014Morphology analysis of near IR sensitized polymer/fullerene organic solar cells by implementing low bandgap heteroanalogue C-/Si-PCPDTBTcitations
- 2014Fullerene Van der Waals Oligomers as Electron Trapscitations
- 2014Reversible vapochromic response of polymer films doped with a highly emissive molecular rotorcitations
- 2013ITO-free and fully solution-processed semitransparent organic solar cells with high fill factorscitations
- 2006Clay-fulleropyrrolidine nanocompositescitations
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article
Enhancing Planar Inverted Perovskite Solar Cells with Innovative Dumbbell‐Shaped HTMs: A Study of Hexabenzocoronene and Pyrene‐BODIPY‐Triarylamine Derivatives
Abstract
<jats:title>Abstract</jats:title><jats:p>Dumbbell‐shaped systems based on PAHs‐BODIPY‐triarylamine hybrids TM‐(01‐04) are designed as novel and highly efficient hole‐transporting materials for usage in planar inverted perovskite solar cells. BODIPY is employed as a bridge between the PAH units, and the effects of the conjugated <jats:italic>π</jats:italic>‐system's covalent attachment and size are investigated. Fluorescence quenching, 3D fluorescence heat maps, and theoretical studies support energy transfer within the moieties. The systems are extremely resistant to UVC 254 nm germicidal light sources and present remarkable thermal stability at degradation temperatures exceeding 350 °C. Integrating these systems into perovskite solar cells results in outstanding power conversion efficiency (PCE), with TM‐02‐based devices exhibiting a PCE of 20.26%. The devices base on TM‐01, TM‐03, and TM‐04 achieve PCE values of 16.98%, 17.58%, and 18.80%, respectively. The long‐term stability of these devices is measured for 600 h, with initial efficiency retention between 94% and 86%. The TM‐04‐based device presents noticeable stability of 94%, better than the reference polymer PTAA with 91%. These findings highlight the exciting potential of dumbbell‐shaped systems based on PAHs‐BODIPY‐triarylamine derivatives for next‐generation photovoltaics.</jats:p>