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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nawaz, Tehseen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Strategic Fabrication of Au4Cu2 NC/ZIF-8 Composite Via In Situ Integration Technique for Enhanced Energy Storage Applicationscitations
- 2024In situ synthesis of oriented Zn-Mn-Co-telluride on precursor free CuOcitations
- 2023Experimental and theoretical insights of binder-free magnesium nickel cobalt selenide star-like nanostructure as electrodecitations
- 2023Structural study of atomically precise doped Au38-xAgx NCs@ ZIF-8 electrode material for energy storage applicationcitations
- 2023Understanding the Diffusion-Dominated Properties of MOF-Derived Ni–Co–Se/C on CuO Scaffold Electrode using Experimental and First Principle Studycitations
- 2022Fabrication of Bimetallic Cu-Ag Nanoparticle-Decorated Poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) and Its Enhanced Catalytic Activity for the Reduction of 4-Nitrophenolcitations
- 2022Comparative study of ternary metal chalcogenides (MX; M= Zn–Co–Ni; X= S, Se, Te)citations
- 2022Factors affecting the growth formation of nanostructures and their impact on electrode materialscitations
Places of action
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article
Understanding the Diffusion-Dominated Properties of MOF-Derived Ni–Co–Se/C on CuO Scaffold Electrode using Experimental and First Principle Study
Abstract
Batteries and supercapacitors continue to be one of the most researched topics in the class of energy storage devices. The continuous development of battery and supercapacitor cell components has shown promising development throughout the years—from slabs of pure metal to porous and tailored structures of metal-based active materials. In this direction, metal–organic frameworks (MOFs) serve great advantages in improving the properties and structure of the derived metal-based active materials. This research provides a novel electrode material, Ni–Co–Se/C@CuO, derived from Ni–Co-MOF integrated with pre-oxidized Cu mesh. The superior electrochemical performance of Ni–Co–Se/C@CuO over Ni–Co-MOF@CuO is evident through its higher specific capacity, lower resistivity, richer redox activity, and more favorable diffusion-dominated storage mechanism. When assembled as a hybrid supercapacitor (HSC), the hybrid device using rGO and Ni–Co–Se/C@CuO as electrodes exhibits a high energy density of 42 W h kg<sup>−1</sup> at a power density of 2 kW kg<sup>−1</sup>, and maintains its capacity retention even after 20 000 cycles. The improved capacity performance is also evaluated using first-principle investigations, revealing that the unique and preserved heterostructure of Ni–Co–Se/C@CuO portrays enhanced metallic properties. Such evaluation of novel electrodes with superior properties may benefit next-generation electrodes for supercapacitor devices. © 2023 Wiley-VCH GmbH.