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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hueso, Luis E.
CIC nanoGUNE
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Circularly Polarized Photoluminescence in Chiral Hybrid Organic–Inorganic Manganese Halide Perovskites: From Bulk Materials to Exfoliated Flakescitations
- 2022Magnetic properties of layered hybrid organic-Inorganic metal-halide perovskites: Transition metal, organic cation and perovskite phase pffectscitations
- 2022Raman spectroscopy in layered hybrid organic-inorganic metal halide perovskites
- 2022Magnetic Properties of Layered Hybrid Organic‐Inorganic Metal‐Halide Perovskites: Transition Metal, Organic Cation and Perovskite Phase Effectscitations
- 2022Spin-to-charge conversion by spin pumping in sputtered polycrystalline Bi$_x$Se$_{1-x}$
- 2022Interface-Assisted Sign Inversion of Magnetoresistance in Spin Valves Based on Novel Lanthanide Quinoline Moleculescitations
- 2022Tailoring photoluminescence by strain-engineering in layered perovskite flakescitations
- 2020Quantification of interfacial spin-charge conversion in hybrid devices with a metal/insulator interfacecitations
- 2019Large multi-directional spin-to-charge conversion in low symmetry semimetal MoTe$_2$ at room temperaturecitations
- 2019Large Multidirectional Spin-to-Charge Conversion in Low-Symmetry Semimetal MoTe2 at Room Temperaturecitations
- 2018Unveiling the mechanisms of the spin Hall effect in Tacitations
- 2016Spin Hall Magnetoresistance as a Probe for Surface Magnetization in Pt=CoFe2O4 Bilayerscitations
- 2013Temperature dependence of spin polarization in ferromagnetic metals using lateral spin valvescitations
- 2008Magnetoresistance and energy model of Alq3-based spintronic devices
Places of action
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article
Magnetic Properties of Layered Hybrid Organic‐Inorganic Metal‐Halide Perovskites: Transition Metal, Organic Cation and Perovskite Phase Effects
Abstract
<jats:title>Abstract</jats:title><jats:p>Understanding the structural and magnetic properties in layered hybrid organic‐inorganic metal halide perovskites (HOIPs) is key for their design and integration in spin‐electronic devices. Here, a systematic study is conducted on ten compounds to understand the effect of the transition metal (Cu<jats:sup>2+</jats:sup>, Mn<jats:sup>2+</jats:sup>, Co<jats:sup>2+</jats:sup>), organic spacer (alkyl‐ and aryl‐ammonium), and perovskite phase (Ruddlesden‐Popper and Dion‐Jacobson) on the properties of these materials. Temperature‐dependent Raman measurements show that the crystals’ structural phase transitions are triggered by the motional freedom of the organic cations as well as by the flexibility of the inorganic metal‐halide lattice. In the case of Cu<jats:sup>2+</jats:sup> HOIPs, an increase of the in‐plane anisotropy and a reduction of the octahedra interlayer distance is found to change the behavior of the HOIP from that of a 2D ferromagnet to that of a quasi‐3D antiferromagnet. Mn<jats:sup>2+</jats:sup> HOIPs show inherent antiferromagnetic octahedra intralayer interactions and a phenomenologically rich magnetism, presenting spin‐canting, spin‐flop transitions, and metamagnetism controlled by the crystal anisotropy. Co<jats:sup>2+</jats:sup> crystals with non‐linked tetrahedra show a dominant paramagnetic behavior irrespective of the organic spacer and the perovskite phase. This study demonstrates that the chemical flexibility of HOIPs can be exploited to develop novel layered magnetic materials with tailored magnetic properties.</jats:p>