693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Welle, Alexander
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (47/47 displayed)
- 2024One-step sputtering of MoSSe metastable phase as thin film and predicted thermodynamic stability by computational methods
- 2024One-step sputtering of MoSSe metastable phase as thin film and predicted thermodynamic stability by computational methodscitations
- 2024Hybrid Two‐Step Inkjet‐Printed Perovskite Solar Cellscitations
- 2024Photo‐Arbuzov Reactions as a Broadly Applicable Surface Modification Strategycitations
- 2024FAIR Data Infrastructure with Enhanced Functionality and Domain Specific Applications
- 2024FAIR Data Infrastructure with Enhanced Functionality and Domain Specific Applications
- 2024Precise determination of oxygen content in SmBa2Cu3O7-δ thin film samples using x-ray diffractioncitations
- 2023Addressing the Sluggish Kinetics of Sulfur Redox for High‐Energy Mg–S Batteriescitations
- 2023Addressing the Sluggish Kinetics of Sulfur Redox for High‐Energy Mg–S Batteriescitations
- 2023The influence of Sb doping on the local structure and disorder in thermoelectric ZnO:Sb thin filmscitations
- 2023Formation of Gold Nanoclusters from Goldcarbonyl Chloride inside the Metal-Organic Framework HKUST-1citations
- 2023Automated classification of granular bainite and polygonal ferrite by electron backscatter diffraction verified through local structural and mechanical analysescitations
- 2023Covalent Adaptable Microstructures via Combining Two‐Photon Laser Printing and Alkoxyamine Chemistry: Toward Living 3D Microstructures
- 2022Identification of Zirconia Particle Uptake in Human Osteoblasts by ToF-SIMS Analysis and Particle-Size Effects on Cell Metabolismcitations
- 2022Covalent Adaptable Microstructures via Combining Two‐Photon Laser Printing and Alkoxyamine Chemistry: Toward Living 3D Microstructurescitations
- 2021Anomalous bulk diffusion of methylene diphenyl diisocyanate in silicone elastomercitations
- 2021Metamorphosis of Heterostructured Surface‐Mounted Metal–Organic Frameworks Yielding Record Oxygen Evolution Mass Activitiescitations
- 2020Molecular Changes in Vapor‐Based Polymer Thin Films Assessed by Characterization of Swelling Properties of Amine‐Functionalized Poly‐p-xylylene
- 2020Chemical vapor deposited polymer layer for efficient passivation of planar perovskite solar cellscitations
- 2020Advanced Bifunctional Oxygen Reduction and Evolution Electrocatalyst Derived from Surface-Mounted Metal-Organic Frameworkscitations
- 2019Mobility of charge carriers in self-assembled monolayerscitations
- 2019Ultrashort Pulsed Laser Surface Patterning of Titanium to Improve Osseointegration of Dental Implantscitations
- 2019Ultrashort Pulsed Laser Surface Patterning of Titanium to Improve Osseointegration of Dental Implantscitations
- 2019Laser-Grafted Molecularly Imprinted Polymers for the Detection of Histamine from Organocatalyzed Atom Transfer Radical Polymerizationcitations
- 2019Photoiniferter Surface Grafting of Poly(methyl acrylate) using Xanthatescitations
- 2018Dynamic Protein Adsorption onto Dendritic Polyglycerol Sulfate Self-Assembled Monolayerscitations
- 2018Oxidative polymerization of terthiophene and a substituted thiophene monomer in metal-organic framework thin filmscitations
- 20182D laser lithography on silicon substrates via photoinduced copper-mediated radical polymerizationcitations
- 20182D laser lithography on silicon substrates via photoinduced copper-mediated radical polymerizationcitations
- 2017Spatially resolved photochemical coding of reversibly anchored cysteine-rich domainscitations
- 2017Facile loading of thin-film surface-anchored metal-organic frameworks with Lewis-base guest moleculescitations
- 2017Facile loading of thin-film surface-anchored metal-organic frameworks with Lewis-base guest moleculescitations
- 2016Solid-material-based Coupling Efficiency Analyzed with Time-of-Flight Secondary Ion Mass Spectrometry
- 2016Controlled radical polymerization and in-depth mass-spectrometric characterization of poly(ionic liquid)s and their photopatterning on surfaces
- 2016Selective Functionalization of Microstructured Surfaces by Laser-Assisted Particle Transfercitations
- 2016Simultaneous dual encoding of three-dimensional structures by light-induced modular ligationcitations
- 2015Designing pi-Conjugated Polymeric Nano- and Microstructures via Light Induced Chemistrycitations
- 2015A Photolithographic Approach to Spatially Resolved Cross-Linked Nanolayerscitations
- 2015Controlled radical polymerization and in-depth mass-spectrometric characterization of poly(ionic liquid)s and their photopatterning on surfacescitations
- 2015Peptide-equipped tobacco mosaic virus templates for selective and controllable biomineral depositioncitations
- 2015Free-Standing Nanomembranes Based on Selective CVD Deposition of Functional Poly- p -xylylenescitations
- 2015Free-Standing Nanomembranes Based on Selective CVD Deposition of Functional Poly- p -xylylenescitations
- 2014Interaction of Human Plasma Proteins with Thin Gelatin-Based Hydrogel Films: A QCM-D and ToF-SIMS Studycitations
- 2014Fabrication and spatially resolved functionalization of 3D microstructures via multiphoton-induced Diels-Alder chemistrycitations
- 2013Site-selective growth of surface-anchored metal-organic frameworks on self-assembled monolayer patterns prepared by AFM nanograftingcitations
- 2013Photochemical generation of light responsive surfacescitations
- 2012Surface characteristics and wettability of magnetron-sputtered oxygen containing amorphous carbon (a-C:O) thin films
Places of action
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article
Covalent Adaptable Microstructures via Combining Two‐Photon Laser Printing and Alkoxyamine Chemistry: Toward Living 3D Microstructures
Abstract
Manufacturing programmable materials, whose mechanical properties can be adapted on demand, is highly desired for their application in areas ranging from robotics, to biomedicine, or microfluidics. Herein, the inclusion of dynamic and living bonds, such as alkoxyamines, in a printable formulation suitable for two-photon 3D laser printing is exploited. On one hand, taking advantage of the dynamic covalent character of alkoxyamines, the nitroxide exchange reaction is investigated. As a consequence, a reduction of the Young´s Modulus by 50%, is measured by nanoindentation. On the other hand, due to its “living” characteristic, the chain extension becomes possible via nitroxide mediated polymerization. In particular, living nitroxide mediated polymerization of styrene results not only in a dramatic increase of the volume (≈8 times) of the 3D printed microstructure but also an increase of the Young's Modulus by two orders of magnitude (from 14 MPa to 2.7 GPa), while maintaining the shape including fine structural details. Thus, the approach introduces a new dimension by enabling to create microstructures with dynamically tunable size and mechanical properties.