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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ronning, Carsten
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Selective Generation of Luminescent Defects in Hexagonal Boron Nitridecitations
- 2023High‐Temperature Laser‐Assisted Synthesis of Boron Nanorods, Nanowires, and Bamboo‐Like Nanotubescitations
- 2023Early oxidation stages of austenitic stainless steel monitored using Mn as tracercitations
- 2023A Combination of Ion Implantation and High‐Temperature Annealing: Donor–Acceptor Pairs in Carbon‐Implanted AlNcitations
- 2022Tuning carrier density and phase transitions in oxide semiconductors using focused ion beamscitations
- 2022Wide‐Bandgap Double Perovskites with Multiple Longitudinal‐Optical Phonon Scatteringcitations
- 2021Fast recovery of ion-irradiation-induced defects in Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> thin films at room temperaturecitations
- 2020Polarization Dependent Excitation and High Harmonic Generation from Intense Mid-IR Laser Pulses in ZnOcitations
- 2020Hot electrons in a nanowire hard X-ray detectorcitations
- 2019Formation of Ag nanoparticles in Si (100) wafers by single and multiple low energy Ag ions implantationcitations
- 2018Dynamics of nanoparticle morphology under low energy ion irradiationcitations
- 2014Electron-beam-induced current at absorber back surfaces of Cu (In,Ga) Se2 thin-film solar cellscitations
- 2013Controlled synthesis of ultrathin ZnO nanowires using micellar gold nanoparticles as catalyst templatescitations
- 2001Superhard, conductive coatings for atomic force microscopy cantileverscitations
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article
Wide‐Bandgap Double Perovskites with Multiple Longitudinal‐Optical Phonon Scattering
Abstract
<jats:title>Abstract</jats:title><jats:p>Alloyed lead‐free double perovskites display intense photoluminescence, are environmentally friendly, and their devices show long‐term operation. Thanks to these properties, which make them excellent warm white‐emitting materials, they have recently received great attention in lighting applications. An important factor to tune the optical properties of alloyed lead‐free double perovskites is the presence of self‐trapped excitons. Here, it is demonstrated that in lead‐free double perovskites, the strong electron–phonon coupling plays a crucial role in the generation of self‐trapped excitons. The strong electron–phonon coupling is confirmed by a large Huang–Rhys factor and by the presence of multiphonon transitions. In particular, sharp emission lines superimposed on the broad photoluminescence emission band of one of these samples (Cs<jats:sub>2</jats:sub>Ag<jats:sub>0.6</jats:sub>Na<jats:sub>0.4</jats:sub>InCl<jats:sub>6</jats:sub> 0.5%Bi) are observed; these are due to the strong coupling of longitudinal‐optical phonons with excited electronic states caused by the tetragonally distorted AgCl<jats:sub>6</jats:sub> octahedrons. Such a strong coupling of longitudinal‐optical phonons to electrons can effectively modulate the photophysical properties of alloyed double perovskites, and its understanding is, thus, of paramount importance for the design of future optoelectronic devices.</jats:p>