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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Liu, Zhen
Vrije Universiteit Brussel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Microfluidic Fabrication of Gadolinium-Doped Hydroxyapatite for Theragnostic Applicationscitations
- 2022A PDTPQx:PC61BM blend with pronounced charge-transfer absorption for organic resonant cavity photodetectors – direct arylation polymerization vs. Stille polycondensationcitations
- 2022A PDTPQx:PC61BM blend with pronounced charge-transfer absorption for organic resonant cavity photodetectors – direct arylation polymerization vs. Stille polycondensationcitations
- 2022Wide‐Bandgap Double Perovskites with Multiple Longitudinal‐Optical Phonon Scatteringcitations
- 2021Ionic liquid and polymer coated garnet solid electrolytes for high-energy solid-state lithium metal batteriescitations
- 2020Comparative study on the effects of alkylsilyl and alkylthio side chains on the performance of fullerene and non-fullerene polymer solar cellscitations
- 2020Comparative study on the effects of alkylsilyl and alkylthio side chains on the performance of fullerene and non-fullerene polymer solar cellscitations
- 2019Competing Interface and Bulk Effect-Driven Magnetoelectric Coupling in Vertically Aligned Nanocomposites.
- 2011Investigation of noble metal nanoparticle ζ-potential effects on single-cell exocytosis function in vitro with carbon-fiber microelectrode amperometrycitations
Places of action
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article
Wide‐Bandgap Double Perovskites with Multiple Longitudinal‐Optical Phonon Scattering
Abstract
<jats:title>Abstract</jats:title><jats:p>Alloyed lead‐free double perovskites display intense photoluminescence, are environmentally friendly, and their devices show long‐term operation. Thanks to these properties, which make them excellent warm white‐emitting materials, they have recently received great attention in lighting applications. An important factor to tune the optical properties of alloyed lead‐free double perovskites is the presence of self‐trapped excitons. Here, it is demonstrated that in lead‐free double perovskites, the strong electron–phonon coupling plays a crucial role in the generation of self‐trapped excitons. The strong electron–phonon coupling is confirmed by a large Huang–Rhys factor and by the presence of multiphonon transitions. In particular, sharp emission lines superimposed on the broad photoluminescence emission band of one of these samples (Cs<jats:sub>2</jats:sub>Ag<jats:sub>0.6</jats:sub>Na<jats:sub>0.4</jats:sub>InCl<jats:sub>6</jats:sub> 0.5%Bi) are observed; these are due to the strong coupling of longitudinal‐optical phonons with excited electronic states caused by the tetragonally distorted AgCl<jats:sub>6</jats:sub> octahedrons. Such a strong coupling of longitudinal‐optical phonons to electrons can effectively modulate the photophysical properties of alloyed double perovskites, and its understanding is, thus, of paramount importance for the design of future optoelectronic devices.</jats:p>