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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zhao-Karger, Zhirong
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Calcium Metal Batteries - Similarities and Differences to their Magnesium and Lithium Counterparts
- 2024Recent developments and future prospects of magnesium–sulfur batteriescitations
- 2023Addressing the Sluggish Kinetics of Sulfur Redox for High‐Energy Mg–S Batteriescitations
- 2023A π‐Conjugated Porphyrin Complex as Cathode Material Allows Fast and Stable Energy Storage in Calcium Batteries
- 2022Dual Role of Mo 6 S 8 in Polysulfide Conversion and Shuttle for Mg–S Batteriescitations
- 2022Operando UV/vis Spectroscopy Providing Insights into the Sulfur and Polysulfide Dissolution in Magnesium-Sulfur Batteriescitations
- 2021Polyoxometalate Modified Separator for Performance Enhancement of Magnesium–Sulfur Batteriescitations
- 2021Surface Engineering of a Mg Electrode via a New Additive to Reduce Overpotentialcitations
- 2020Multi‐Electron Reactions Enabled by Anion‐Based Redox Chemistry for High‐Energy Multivalent Rechargeable Batteriescitations
- 2020Multi-electron reactions enabled by anion-participated redox chemistry for high-energy multivalent rechargeable batteriescitations
- 2014Carbon materials for the positive electrode in all-vanadium redox flow batteriescitations
- 2014Gold Catalysis: AuCl-induced Polymerization of Styrene and n-Butylvinylethercitations
- 2014Fabrication of porous rhodium nanotube catalysts by electroless platingcitations
- 2012Fabrication of porous rhodium nanotube catalysts by electroless platingcitations
Places of action
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article
Polyoxometalate Modified Separator for Performance Enhancement of Magnesium–Sulfur Batteries
Abstract
<jats:title>Abstract</jats:title><jats:p>The magnesium–sulfur (Mg‐S) battery has attracted considerable attention as a candidate of post‐lithium battery systems owing to its high volumetric energy density, safety, and cost effectiveness. However, the known shuttle effect of the soluble polysulfides during charge and discharge leads to a rapid capacity fade and hinders the realization of sulfur‐based battery technology. Along with the approaches for cathode design and electrolyte formulation, functionalization of separators can be employed to suppress the polysulfide shuttle. In this study, a glass fiber separator coated with decavanadate‐based polyoxometalate (POM) clusters/carbon composite is fabricated by electrospinning technique and its impacts on battery performance and suppression of polysulfide shuttling are investigated. Mg–S batteries with such coated separators and non‐corrosive Mg[B(hfip)<jats:sub>4</jats:sub>]<jats:sub>2</jats:sub> electrolyte show significantly enhanced reversible capacity and cycling stability. Functional modification of separator provides a promising approach for improving metal–sulfur batteries.</jats:p>