| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Daasbjerg, Kim
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2023Interfacial Engineering of PVDF-TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applicationscitations
- 2023Interfacial Engineering of PVDF-TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applicationscitations
- 2023Steering carbon dioxide reduction toward C–C coupling using copper electrodes modified with porous molecular filmscitations
- 2023Interfacial Engineering of PVDF‐TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applicationscitations
- 2022Can the CO 2 Reduction Reaction Be Improved on Cu:Selectivity and Intrinsic Activity of Functionalized Cu Surfacescitations
- 2022Can the CO2Reduction Reaction Be Improved on Cucitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO 2 Reduction to Formatecitations
- 2020Achieving Near-Unity CO Selectivity for CO 2 Electroreduction on an Iron-Decorated Carbon Materialcitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO<sub>2</sub> Reduction to Formatecitations
- 2020Stimuli-responsive degrafting of polymer brushes via addressable catecholato-metal attachmentscitations
- 2020Stimuli-responsive degrafting of polymer brushes via addressable catecholato-metal attachmentscitations
- 2020Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrodecitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective $CO_{2}$ Reduction to Formatecitations
- 2020Facile Access to Disulfide/Thiol Containing Poly(glycidyl methacrylate) Brushes as Potential Rubber Adhesive Layerscitations
- 2020Facile Access to Disulfide/Thiol Containing Poly(glycidyl methacrylate) Brushes as Potential Rubber Adhesive Layerscitations
- 2018Facile Synthesis of Iron- and Nitrogen-Doped Porous Carbon for Selective CO 2 Electroreductioncitations
- 2018Efficient bonding of ethylene-propylene-diene M-class rubber to stainless steel using polymer brushes as a nanoscale adhesivecitations
- 2017Efficient Graphene Production by Combined Bipolar Electrochemical Intercalation and High-Shear Exfoliationcitations
- 2016Hydrophilic Polymer Brush Layers on Stainless Steel Using Multilayered ATRP Initiator Layercitations
- 2016Electrochemical procedure for constructing poly(phenylene sulfide) brushes on glassy carbon and stainless steelcitations
- 2014Durability of PEEK adhesive to stainless steel modified with aryldiazonium saltscitations
Places of action
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article
Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO<sub>2</sub> Reduction to Formate
Abstract
<jats:title>Abstract</jats:title><jats:p>Recently, a large number of nanostructured metal‐containing materials have been developed for the electrochemical CO<jats:sub>2</jats:sub> reduction reaction (eCO<jats:sub>2</jats:sub>RR). However, it remains a challenge to achieve high activity and selectivity with respect to the metal load due to the limited concentration of surface metal atoms. Here, it is reported that the bismuth‐based metal–organic framework Bi(1,3,5‐tris(4‐carboxyphenyl)benzene), herein denoted Bi(btb), works as a precatalyst and undergoes a structural rearrangement at reducing potentials to form highly active and selective catalytic Bi‐based nanoparticles dispersed in a porous organic matrix. The structural change is investigated by electron microscopy, X‐ray diffraction, total scattering, and spectroscopic techniques. Due to the periodic arrangement of Bi cations in highly porous Bi(btb), the in situ formed Bi nanoparticles are well‐dispersed and hence highly exposed for surface catalytic reactions. As a result, high selectivity over a broad potential range in the eCO<jats:sub>2</jats:sub>RR toward formate production with a Faradaic efficiency up to 95(3)% is achieved. Moreover, a large current density with respect to the Bi load, i.e., a mass activity, up to 261(13) A g<jats:sup>−1</jats:sup> is achieved, thereby outperforming most other nanostructured Bi materials.</jats:p>