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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Geaney, Hugh
University of Limerick
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Lithiophilic interlayer driven 'bottom-up' metal infilling in high current density Li-metal anodescitations
- 2024Strategies to Spatially Guide Li Deposition in Porous Electrodes for High-Performance Lithium Metal Batteries
- 2023Lithiophilic Nanowire Guided Li Deposition in Li Metal Batteriescitations
- 2023Solid–Electrolyte Interface Formation on Si Nanowires in Li-Ion Batteries: The Impact of Electrolyte Additivescitations
- 2023Cu Current Collector with Binder‐Free Lithiophilic Nanowire Coating for High Energy Density Lithium Metal Batteriescitations
- 2021Amorphization driven Na-alloying in Si<sub><i>x</i></sub>Ge<sub>1−<i>x</i></sub> alloy nanowires for Na-ion batteriescitations
- 2021Direct Growth of Si, Ge, and Si–Ge Heterostructure Nanowires Using Electroplated Zn: An Inexpensive Seeding Technique for Li‐Ion Alloying Anodescitations
- 20202D SnSe nanonetworks; growth and evaluation for Li-ion battery applications
- 2019Multimodal surface analyses of chemistry and structure of biominerals in rodent pineal gland concretionscitations
- 2018Copper Sulfide (Cu<i><sub>x</sub></i>S) Nanowire‐in‐Carbon Composites Formed from Direct Sulfurization of the Metal‐Organic Framework HKUST‐1 and Their Use as Li‐Ion Battery Cathodescitations
Places of action
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article
Copper Sulfide (Cu<i><sub>x</sub></i>S) Nanowire‐in‐Carbon Composites Formed from Direct Sulfurization of the Metal‐Organic Framework HKUST‐1 and Their Use as Li‐Ion Battery Cathodes
Abstract
<jats:title>Abstract</jats:title><jats:p>Li‐ion batteries containing cost‐effective, environmentally benign cathode materials with high specific capacities are in critical demand to deliver the energy density requirements of electric vehicles and next‐generation electronic devices. Here, the phase‐controlled synthesis of copper sulfide (Cu<jats:italic><jats:sub>x</jats:sub></jats:italic>S) composites by the temperature‐controlled sulfurization of a prototypal Cu metal‐organic framework (MOF), HKUST‐1 is reported. The tunable formation of different Cu<jats:italic><jats:sub>x</jats:sub></jats:italic>S phases within a carbon network represents a simple method for the production of effective composite cathode materials for Li‐ion batteries. A direct link between the sulfurization temperature of the MOF and the resultant Cu<jats:italic><jats:sub>x</jats:sub></jats:italic>S phase formed with more Cu‐rich phases favored at higher temperatures is further shown. The Cu<jats:italic><jats:sub>x</jats:sub></jats:italic>S/C samples are characterized through X‐ray diffraction (XRD), thermogravimetric analysis (TGA), transmission electron microscopy, and energy dispersive X‐ray spectroscopy (EDX) in addition to testing as Li‐ion cathodes. It is shown that the performance is dependent on both the Cu<jats:italic><jats:sub>x</jats:sub></jats:italic>S phase and the crystal morphology with the Cu<jats:sub>1.8</jats:sub>S/C‐500 material as a nanowire composite exhibiting the best performance, showing a specific capacity of 220 mAh g<jats:sup>−1</jats:sup> after 200 charge/discharge cycles.</jats:p>