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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Krupp, Ulrich
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2024Using additive manufacturing to process precipitation-strengthened high conductive copper alloys
- 2024Automated Workflow for Phase‐Field Simulations: Unveiling the Impact of Heat‐Treatment Parameters on Bainitic Microstructure in Steelcitations
- 2024Effects of silicon and aluminum alloying on phase transformation and microstructure evolution in fe–0.2c–2.5mn steel: insights from continuous–cooling–transformation and time–temperature–transformation diagramscitations
- 2024The influence of microstructural heterogeneities on high-temperature mechanical properties of additively manufactured γ'-forming Ni-based alloyscitations
- 2024Manufacturing and aging behavior of CuCr1Zr powder: Analysis and modelling of close-coupled gas atomization of CuCr1Zr and its impact on the melt beam disintegration and analysis powder oxidation kineticscitations
- 2024The dispersion-strengthening effect of tin nanoparticles evoked by ex situ nitridation of gas-atomized, nicu-based alloy 400 in fluidized bed reactor for laser powder bed fusioncitations
- 2023Influence of Transformation Temperature on the High‐Cycle Fatigue Performance of Carbide‐Bearing and Carbide‐Free Bainitecitations
- 2022Surface layer microstructure evolution during interdiffusion annealing of chromium electroplated iron substrates
- 2022Alloy and process design of forging steels for better environmental performancecitations
- 2022Surface or Internal Fatigue Crack Initiation during VHCF of Tempered Martensitic and Bainitic Steels : Microstructure and Frequency/Strain Rate Dependencycitations
- 2021Investigation of Alloy‐Dependent Occurrence of Ferromagnetism in Carbon‐Expanded Austenitic Steel after Low‐Temperature Surface Hardening
- 2021On the Influence of Control Type and Strain Rate on the Lifetime of 50CrMo4
- 2021Quasi Static and Fatigue Properties of Long Carbon Fiber Reinforced Polyamidecitations
- 2021The Effect of Cu Content and Surface Finish on the Metal Dusting Resistance of Additively Manufactured NiCu Alloyscitations
- 2021Aachen-Heerlen annotated steel microstructure datasetcitations
- 2021Bauschinger effect and latent hardening under cyclic micro-bending of Ni-base Alloy 718 single crystals: Part II. Single crystal plasticity modeling with latent kinematic hardeningcitations
- 2021Investigation of Fatigue Damage of Tempered Martensitic Steel during High Cycle Fatigue and Very High Cycle Fatigue Loading Using In Situ Monitoring by Scanning Electron Microscope and High‐Resolution Thermographycitations
- 2021Bauschinger effect and latent hardening under cyclic micro-bending of Ni-base Alloy 718 single crystals: Part I. Experimental analysis of single and multi slip plasticitycitations
- 2020On the Influence of Control Type and Strain Rate on the Lifetime of 50CrMo4citations
- 2019Formation of corrosion pockets in FeNiCrAl at high temperatures investigated by 3D FIB‐SEM tomographycitations
- 2018Structural Loading of Cellular Metalscitations
- 2017Electro-oxidation of a cobalt based steel in LiOH: a non-noble metal based electro-catalyst suitable for durable water-splitting in an acidic milieucitations
- 2017Investigation of changing failure mechanisms in the VHCF regime caused by different strengths of a martensitic steel
- 2016Electro-oxidation of Ni42 steel: A highly active bifunctional electrocatalystcitations
- 2016Electro‐Oxidation of Ni42 Steel: A Highly Active Bifunctional Electrocatalystcitations
- 2015Brittle failure of metallic foams under tensile and cyclic loading - experimental studies and standardization ; Sprödbruch von metalischen Schäumen unter Zug- und zyklischen Belastungen
- 2008On the Mutual Interaction between Mechanical Stresses and Internal Corrosion during Isothermal and Cyclic Oxidation of Nickel-Base Superalloys
- 2007The Influence of Specimen Thickness on the High Temperature Corrosion Behavior of CMSX-4 during Thermal-Cycling Exposurecitations
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article
Electro‐Oxidation of Ni42 Steel: A Highly Active Bifunctional Electrocatalyst
Abstract
<jats:p>Janus type water‐splitting catalysts have attracted highest attention as a tool of choice for solar to fuel conversion. AISI Ni42 steel is upon harsh anodization converted into a bifunctional electrocatalyst. Oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are highly efficiently and steadfast catalyzed at pH 7, 13, 14, 14.6 (OER) and at pH 0, 1, 13, 14, 14.6 (HER), respectively. The current density taken from long‐term OER measurements in pH 7 buffer solution upon the electro‐activated steel at 491 mV overpotential (<jats:italic>η</jats:italic>) is around four times higher (4 mA cm<jats:sup>−2</jats:sup>) in comparison with recently developed OER electrocatalysts. The very strong voltage–current behavior of the catalyst shown in OER polarization experiments at both pH 7 and at pH 13 are even superior to those known for IrO<jats:sub>2</jats:sub>‐RuO<jats:sub>2</jats:sub>. No degradation of the catalyst is detected even when conditions close to standard industrial operations are applied to the catalyst. A stable Ni‐, Fe‐oxide based passivating layer sufficiently protects the bare metal for further oxidation. Quantitative charge to oxygen (OER) and charge to hydrogen (HER) conversion are confirmed. High‐resolution XPS spectra show that most likely γ−NiO(OH) and FeO(OH) are the catalytic active OER and NiO is the catalytic active HER species.</jats:p>