| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Kuepper, Karsten
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Influence of Oxygen Plasma on the Growth and Stability of Epitaxial NiCo$_2$O$_4$ Ultrathin Films on Various Substratescitations
- 2022Time-resolved x-ray diffraction and photoelectron spectroscopy investigation of the reactive molecular beam epitaxy of Fe$_3$O$_4$ ultrathin filmscitations
- 2021Cationic Ordering and Its Influence on the Magnetic Properties of Co-Rich Cobalt Ferrite Thin Films Prepared by Reactive Solid Phase Epitaxy on Nb-Doped SrTiO3(001)citations
- 2016Electro-oxidation of Ni42 steel: A highly active bifunctional electrocatalystcitations
- 2016Electro‐Oxidation of Ni42 Steel: A Highly Active Bifunctional Electrocatalystcitations
- 2015Magnetic anisotropy related to strain and thickness of ultrathin iron oxide films on MgO(001)citations
- 2015Modifying magnetic properties of ultra-thin magnetite films by growth on Fe pre-covered MgO(001)citations
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article
Electro‐Oxidation of Ni42 Steel: A Highly Active Bifunctional Electrocatalyst
Abstract
<jats:p>Janus type water‐splitting catalysts have attracted highest attention as a tool of choice for solar to fuel conversion. AISI Ni42 steel is upon harsh anodization converted into a bifunctional electrocatalyst. Oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are highly efficiently and steadfast catalyzed at pH 7, 13, 14, 14.6 (OER) and at pH 0, 1, 13, 14, 14.6 (HER), respectively. The current density taken from long‐term OER measurements in pH 7 buffer solution upon the electro‐activated steel at 491 mV overpotential (<jats:italic>η</jats:italic>) is around four times higher (4 mA cm<jats:sup>−2</jats:sup>) in comparison with recently developed OER electrocatalysts. The very strong voltage–current behavior of the catalyst shown in OER polarization experiments at both pH 7 and at pH 13 are even superior to those known for IrO<jats:sub>2</jats:sub>‐RuO<jats:sub>2</jats:sub>. No degradation of the catalyst is detected even when conditions close to standard industrial operations are applied to the catalyst. A stable Ni‐, Fe‐oxide based passivating layer sufficiently protects the bare metal for further oxidation. Quantitative charge to oxygen (OER) and charge to hydrogen (HER) conversion are confirmed. High‐resolution XPS spectra show that most likely γ−NiO(OH) and FeO(OH) are the catalytic active OER and NiO is the catalytic active HER species.</jats:p>