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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wollschläger, Joachim
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2023Real-Time Monitoring of Strain Accumulation and Relief during Epitaxy of Ultrathin Co Ferrite Films with Varied Co Content
- 2022Real-Time Monitoring the Growth of Epitaxial CoxFe3−xO4 Ultrathin Films on Nb-Doped SrTiO3(001) via Reactive Molecular Beam Epitaxy by Means of Operando HAXPES
- 2022Influence of Oxygen Plasma on the Growth and Stability of Epitaxial NiCo2O4 Ultrathin Films on Various Substrates
- 2021Quantitative comparison of the magnetic proximity effect in Pt detected by XRMR and XMCDcitations
- 2021Quantitative comparison of the magnetic proximity effect in Pt detected by XRMR and XMCDcitations
- 2021Cationic Ordering and Its Influence on the Magnetic Properties of Co-Rich Cobalt Ferrite Thin Films Prepared by Reactive Solid Phase Epitaxy on Nb-Doped SrTiO3(001)citations
- 2021Magnetoelectric Response of Laminated Cantilevers Comprising a Magnetoactive Elastomer and a Piezoelectric Polymer, in Pulsed Uniform Magnetic Fieldscitations
- 2019Quadratic magneto-optic Kerr effect spectroscopy of Fe epitaxial films on MgO(001) substratescitations
- 2018Quadratic magnetooptic spectroscopy setup based on photoelastic light modulationcitations
- 2018Formation routes and structural details of the CaF1 layer on Si(111) from high-resolution noncontact atomic force microscopy datacitations
- 2017Electro-oxidation of a cobalt based steel in LiOH: a non-noble metal based electro-catalyst suitable for durable water-splitting in an acidic milieucitations
- 2017Quantitative Disentanglement of the Spin Seebeck, Proximity-Induced, and Ferromagnetic-Induced Anomalous Nernst Effect in Normal-Metal–Ferromagnet Bilayerscitations
- 2016Electro-oxidation of Ni42 steel: A highly active bifunctional electrocatalystcitations
- 2016Electro‐Oxidation of Ni42 Steel: A Highly Active Bifunctional Electrocatalystcitations
- 2015Magnetic anisotropy related to strain and thickness of ultrathin iron oxide films on MgO(001)citations
- 2015Frontiers in Neuroscience / Tunnel junction based memristors as artificial synapsescitations
- 2015Modifying magnetic properties of ultra-thin magnetite films by growth on Fe pre-covered MgO(001)citations
- 2015Stainless steel made to rust: a robust water-splitting catalyst with benchmark characteristicscitations
- 2015Tunnel junction based memristors as artificial synapsescitations
- 2014Ultrathin, epitaxial cerium dioxide on siliconcitations
- 2012X-ray diffraction study on size effects in epitaxial magnetite thin films on MgO(0 0 1)citations
- 2011In-situ x-ray diffraction studies on post-deposition vacuum-annealing of ultra-thin iron oxide filmscitations
- 2010Improved epitaxy of ultrathin praseodymia films on chlorine passivated Si(111) reducing silicate interface formationcitations
- 2009Defect structure of Ge(111)/cubic Pr2O3(111)/Si(111) heterostructures: Thickness and annealing dependencecitations
- 2009Postdeposition annealing induced transition from hexagonal Pr2O3 to cubic PrO2 films on Si(111)citations
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article
Electro‐Oxidation of Ni42 Steel: A Highly Active Bifunctional Electrocatalyst
Abstract
<jats:p>Janus type water‐splitting catalysts have attracted highest attention as a tool of choice for solar to fuel conversion. AISI Ni42 steel is upon harsh anodization converted into a bifunctional electrocatalyst. Oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are highly efficiently and steadfast catalyzed at pH 7, 13, 14, 14.6 (OER) and at pH 0, 1, 13, 14, 14.6 (HER), respectively. The current density taken from long‐term OER measurements in pH 7 buffer solution upon the electro‐activated steel at 491 mV overpotential (<jats:italic>η</jats:italic>) is around four times higher (4 mA cm<jats:sup>−2</jats:sup>) in comparison with recently developed OER electrocatalysts. The very strong voltage–current behavior of the catalyst shown in OER polarization experiments at both pH 7 and at pH 13 are even superior to those known for IrO<jats:sub>2</jats:sub>‐RuO<jats:sub>2</jats:sub>. No degradation of the catalyst is detected even when conditions close to standard industrial operations are applied to the catalyst. A stable Ni‐, Fe‐oxide based passivating layer sufficiently protects the bare metal for further oxidation. Quantitative charge to oxygen (OER) and charge to hydrogen (HER) conversion are confirmed. High‐resolution XPS spectra show that most likely γ−NiO(OH) and FeO(OH) are the catalytic active OER and NiO is the catalytic active HER species.</jats:p>