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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schenning, Aphj Albert
Eindhoven University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (37/37 displayed)
- 2023Melt-Extruded Thermoplastic Liquid Crystal Elastomer Rotating Fiber Actuatorscitations
- 2023Switching between 3D surface topographies in liquid crystal elastomer coatings using two-step imprint lithographycitations
- 2022Hydrogen-Bonded Supramolecular Liquid Crystal Polymers: Smart Materials with Stimuli-Responsive, Self-Healing, and Recyclable Propertiescitations
- 2021NIR–vis–UV Light-Responsive High Stress-Generating Polymer Actuators with a Reduced Creep Ratecitations
- 2021Patterned Actuators via Direct Ink Writing of Liquid Crystalscitations
- 2020Stimuli-Responsive Shape Changing Commodity Polymer Composites and Bilayerscitations
- 2020Direct Laser Writing of Four-Dimensional Structural Color Microactuators Using a Photonic Photoresistcitations
- 2019An untethered magnetic- and light-responsive rotary gripper: shedding light on photoresponsive liquid crystal actuatorscitations
- 20193D helix engineering in chiral photonic materialscitations
- 2018Hydrogen-bonded siloxane liquid crystals for hybrid nanomaterials
- 2018Stimuli-responsive polymer film or coating prepared by mixing in a suitable fashion a side chain liquid crystalline polymer with reactive mesogens and responsive devices:process for preparing the same
- 2018Stimuli-responsive polymer film or coating prepared by mixing in a suitable fashion a side chain liquid crystalline polymer with reactive mesogens and responsive devices
- 2017A rewritable, reprogrammable, dual light-responsive polymer actuatorcitations
- 2017Anisotropic dye adsorption and anhydrous proton conductivity in smectic liquid crystal networks:the role of cross-link density, order, and orientation
- 2017Photonic shape memory polymer with stable multiple colorscitations
- 2017Easily processable temperature-responsive infrared-reflective polymer coatings
- 2016Regulating the modulus of a chiral liquid crystal polymer network by lightcitations
- 2016A chaotic self-oscillating sunlight driven polymer actuatorcitations
- 2016Stimuli-responsive liquid crystalline materialscitations
- 2015Hydrogen bonding in supramolecular nanoporous materials
- 2015Stimuli-responsive materials based on interpenetrating polymer liquid crystal hydrogelscitations
- 2015Nanoporous adsorbent material for removing species from an aqueous solution
- 2015Liquid crystal polymer membranescitations
- 2014Humidity-responsive liquid crystalline polymer actuators with an asymmetry in the molecular trigger that bend, fold, and curlcitations
- 2014Responsive nanoporous smectic liquid drystal polymer networks as efficient and selective adsorbentscitations
- 2014Accordion-like actuators of multiple 3D patterned liquid crystal polymer filmscitations
- 2014The role of supramolecular chemistry in stimuli responsive and hierarchically structured functional organic materials
- 2014An optical sensor for volatile amines based on an inkjet-printed, hydrogen-bonded, cholesteric liquid crystalline filmcitations
- 2014An optical sensor for volatile amines based on an inkjet-printed, hydrogen-bonded, cholesteric liquid crystalline film
- 2014Optical and topographic changes in water-responsive patterned cholesteric liquid crystalline polymer coatingscitations
- 2013Photoswitchable hydrogel surface topographies by polymerisation-induced diffusioncitations
- 2012Engineering of complex order and the macroscopic deformation of liquid crystal polymer networkscitations
- 2012Printable optical sensors based on H-bonded supramolecular cholesteric liquid crystal networkscitations
- 2008Molecular weight optimum in the mesoscopic order of chiral fluorene (Co)polymer filmscitations
- 2003Highly emissive supramolecular oligo(p-phenylene vinylene) dendrimers
- 2002A soluble equivalent of the supramolecular, quasi-one-dimensional, semiconducting Magnus' green saltcitations
- 2001Synthesis and properties of self organising semiconducting and luminescent polymers and model compounds
Places of action
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article
Responsive nanoporous smectic liquid drystal polymer networks as efficient and selective adsorbents
Abstract
An efficient and selective porous nanostructured polymer adsorbent is prepared from smectic liquid crystals. The adsorption study is performed by using hydrophilic dyes as water pollutants. The anionic pore interior of the nanoporous polymer is able to selectively adsorb cationic methylene blue over anionic methyl orange. Even zwitter ionic rhodamine B could hardly be adsorbed due to the presence of the anionic group in this dye. The confined pore dimensions allow size selective adsorption; a 4th generation cationic dendrimer is not able to diffuse into the nanometer sized pores. The porous nature of the polymer provides easy and fast accessibility of all adsorption sites. Stoichiometric ion exchange is obtained, which equates to an adsorption capacity of nearly 1 gram of methylene blue per 1 gram adsorbent. A competitive Langmuir adsorption constant and pseudo second order rate constant are determined. The adsorbent and adsorbate could both be retrieved after acid treatment of the polymer.