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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pergolesi, Daniele
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Anionic disorder and its impact on the surface electronic structure of oxynitride photoactive semiconductors
- 2023Momentum-resolved electronic structure of LaTiO2N photocatalysts by resonant Soft-X-ray ARPEScitations
- 2022Large imprint in epitaxial 0.67Pb(Mg<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>-0.33PbTiO<sub>3</sub> thin films for piezoelectric energy harvesting applicationscitations
- 2021Heteroepitaxial Hexagonal (00.1) CuFeO2 Thin Film Grown on Cubic (001) SrTiO3 Substrate Through Translational and Rotational Domain Matchingcitations
- 2020Thickness-dependent microstructural properties of heteroepitaxial (00.1) CuFeO2 thin films on (00.1) sapphire by pulsed laser depositioncitations
- 2019Zigzag or spiral-shaped nanostructures improve mechanical stability in yttria-stabilized zirconia membranes for micro-energy conversion devicescitations
- 2017Anisotropic Proton and Oxygen Ion Conductivity in Epitaxial Ba2In2O5 Thin Filmscitations
- 2017Anisotropic Proton and Oxygen Ion Conductivity in Epitaxial Ba 2 In 2 O 5 Thin Filmscitations
- 2016TiN-buffered substrates for photoelectrochemical measurements of oxynitride thin filmscitations
- 2015Probing the bulk ionic conductivity by thin film hetero-epitaxial engineeringcitations
- 2009Fabrication and Electrochemical Properties of Epitaxial Samarium-Doped Ceria Films on SrTiO3-Buffered MgO Substratescitations
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article
Fabrication and Electrochemical Properties of Epitaxial Samarium-Doped Ceria Films on SrTiO3-Buffered MgO Substrates
Abstract
Thin films of samarium-oxide-doped (20 mol%) ceria (SDC) are grown by pulsed-laser deposition (PLD) on (001) MgO single-crystal substrates. SrTiO3 (STO) prepared by PLD is used as a buffer layer on the MgO substrates to enable epitaxial growth of the fluorite-structured SDC film; the STO layer provides a proper crystalline match between SDC and MgO, resulting in highly crystalline, epitaxial SDC films grown in the (001) orientation. Film conductivity is evaluated by electrochemical impedance spectroscopy measurements, which are performed at various temperatures (400–775 °C) in a wide range of oxygen partial pressure (pO2) values (10−25−1 atm) in order to separate ionic and electronic conductivity contributions. At 700 °C, SDC/STO films on (100) MgO exhibit a dominant ionic conductivity of about 7 × 10−2 S cm−1, down to pO2 values of about 10−15 atm. The absence of grain boundaries make the SDC/STO/MgO heterostructures stable to oxidation-reduction cycles at high temperatures, in contrast to that observed for the more disordered SDC/STO films, which degraded after hydrogen exposure.