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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kondarage, Yashodha
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article
Ti3C2Tx MXene-Reinforced Natural Rubber Nanocomposites with Tailored Mechanical and Antiaging Properties
Abstract
<div class="article-section__content en main"><p>Recently, MXene has been identified as a novelreinforcing material for elastomers. Also, the free-radical scavengingability of MXene can be used to improve the antiaging properties ofunsaturated elastomers, such as natural rubber (NR). Herein, Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub>MXene is incorporated into NR at 0–0.8 wt% to investigate themechanical and antiaging properties of NR/MXene nanocomposites (NRMX).The resultant nanocomposites with increasing MXene content show improvedtensile properties and storage modulus due to the homogeneousdistribution of MXene in the nanocomposite, interfacial interactionbetween MXene and NR molecules, and immobilization of NR polymer chainsby MXene. Also, the reduced permanent deformation and hysteresisindicate a lowered heat build-up with increasing MXene concentration.Finally, the improved mechanical properties retention, increased glasstransition temperature, reduced free radical, and –OH and CO formationupon accelerated aging confirm the enhancement of the antiagingproperties of NRMX nanocomposites.</p></div>