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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Steinhorst, Maximilian
Fraunhofer Institute for Material and Beam Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2023Modelling and corrosion of coated stainless steel substrates for bipolar plates at different temperaturescitations
- 2022Pulsed direct-current reactive sputtering of high Young's modulus [002] oriented aluminum nitride thin filmscitations
- 2022Influence of Deposition Temperature on the Electrical and Electrochemical Properties of Carbon-Based Coatings for Metallic Bipolar Plates, Prepared by Cathodic Arc Evaporation
- 2022Development of a Graphite Coating and its Transfer from Batch to Coil Process for Application in PEMFC for Hydrogen-Powered Vehicles
- 2019Investigation of carbon-based coatings on austenitic stainless steel for bipolar plates in proton exchange membrane fuel cells, produced by cathodic arc deposition
- 2019Highly Compact TiO<sub>2</sub> Films by Spray Pyrolysis and Application in Perovskite Solar Cellscitations
- 2019Investigation of carbon-based coatings on austenitic stainless steel for bipolar plates in proton exchange membrane fuel cells, produced by cathodic arc deposition ; Untersuchung von Kohlenstoff-basierten Beschichtungen auf authentischen Edelstahl für Bipolarplatten in Proton-Austausch-Membran Brennstoffzelle, hergestellt mit kathodischen Lichtbogenverdampfen
Places of action
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article
Highly Compact TiO<sub>2</sub> Films by Spray Pyrolysis and Application in Perovskite Solar Cells
Abstract
<jats:sec><jats:label /><jats:p>Transparent and pinhole free hole‐blocking layers such as TiO<jats:sub>2</jats:sub> grown at low temperatures and by scalable processes are necessary to reduce production costs and thus enabling commercialization of perovskite solar cells. Here, the authors compare the transport properties of TiO<jats:sub>2</jats:sub> compact layers grown by spray pyrolysis from commonly used titanium diisopropoxide bisacetylacetonate ([Ti(OPr<jats:sup>i</jats:sup>)<jats:sub>2</jats:sub>(acac)<jats:sub>2</jats:sub>]) precursor to films grown by spray pyrolysis of TiCl<jats:sub>4</jats:sub>. Spray pyrolysis provides insights into the interdependence of precursor chemistry and electron transport properties of TiO<jats:sub>2</jats:sub> films and their influence on the performance of the perovskite solar cells. X‐ray diffraction and X‐ray photoelectron spectroscopy data confirm the chemical and structural composition of the obtained films. Thin film deposition at lower temperature (150 °C) are conducted using TiCl<jats:sub>4</jats:sub> to evaluate the influence of crystal growth and topography by scanning electron microscopy and atomic force microscopy as well as thickness (profilometry) and transmittance (UV/Vis spectroscopy) on the power conversion efficiency of perovskite solar cells. TiO<jats:sub>2</jats:sub> compact layers grown from TiCl<jats:sub>4</jats:sub> enhance the power conversion efficiency by acting as superior electron transfer medium and by reducing hysteresis behavior, when compared to films grown using titanium diisopropoxide bisacetylacetonate. UV/Vis spectroscopy and external quantum efficiency studies reveal the correlation of transmittance on the power conversion efficiency.</jats:p></jats:sec>