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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wolfahrt, Markus
Polymer Competence Center Leoben (Austria)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Redox cationic frontal polymerization: a rapid curing approach for carbon fiber-reinforced composites with high fiber contentcitations
- 2024Design of Reversible Adhesives by Using a Triple Function of Ionic Liquidscitations
- 2023Redox cationic frontal polymerizationcitations
- 2023Tensile properties of flexible composites with knitted reinforcements from various yarn materialscitations
- 2022Testing mechanical performance of adhesively bonded composite joints in engineering applications: an overviewcitations
- 2021Testing mechanical performance of adhesively bonded composite joints in engineering applicationscitations
- 2019Analysis of the Macroscopic Behaviour of PMI Foamcitations
- 2019Bonded aerospace repairs under tensile loading: Wet chemical surface treatment and selected environmental conditionscitations
- 2016Thiol-Ene versus Binary Thiol–Acrylate Chemistrycitations
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article
Thiol-Ene versus Binary Thiol–Acrylate Chemistry
Abstract
<p>The versatile nature of photo-induced thiol-ene chemistry has made it one of the most popular reactions in the design of polymer networks. In the present work, the structure of uniform thiol-ene and complex binary thiol-acrylate networks are studied in detail by photopolymerizing cycloaliphatic and linear alkyl thiols with an allyl monomer and its acrylic counterpart. Along with the crosslink kinetics, the balance between step growth and chain growth mechanism of the two different systems is investigated by FT-IR spectroscopy. Low field NMR experiments are carried out to obtain an insight into the chain dynamics and structure of the photopolymer networks. In addition, tensile properties and glass transition temperature are determined to correlate network properties with mechanical performance.</p>