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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mendis, Cl
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2020Thixomolded AZ91D and MRI153M magnesium alloys and their enhanced corrosion resistancecitations
- 2019Mechanical and Corrosion Properties of Two Precipitation-Hardened Mg-Y-Nd-Gd-Dy Alloys with Small Changes in Chemical Compositioncitations
- 2018Precipitation hardening on mechanical and corrosion properties of extruded Mg10Gd modified with Nd and La ; MDPIcitations
- 2017Hierarchically organized Li–Al-LDH nano-flakes: a low-temperature approach to seal porous anodic oxide on aluminum alloyscitations
- 2016Hot tearing susceptibility of Mg-5Nd-xZn alloys
- 2016In situ synchrotron radiation diffraction investigation of the compression behaviour at 350 °C of ZK40 alloys with addition of CaO and Ycitations
- 2016Thermodynamic description of reactions between Mg and CaOcitations
- 2011Microstructures and tensile properties of a twin roll cast and heat-treated Mg-2.4Zn-0.1Ag-0.1Ca-0.1Zr alloycitations
Places of action
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conferencepaper
Thermodynamic description of reactions between Mg and CaO
Abstract
CaO is considered as possible replacement for cover gases such as SF6 during melting and casting of Mg alloys. Such CaO additions to molten Mg increase the ignition resistance by forming a protective oxide layer. The actual reactions between liquid Mg and CaO are not well understood. An approach based on chemical reaction equations cannot capture the "CaO dissolution" process. This work presents the development of a consistent thermodynamic description of the ternary Mg-Ca-O alloy system. To that end a revision of the thermodynamic data of key oxides, CaO and MgO, has been performed based on original experimental work so far not considered in thermodynamic databases or tabulations. The formation of a liquid Mg-Ca-[O] alloy during the reaction is predicted from the thermodynamic calculations at melting temperatures; solidification simulations are also performed. These predictions from thermodynamic simulations are validated by experimental data using in situ synchrotron radiation diffraction.