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Ferrari, A. |
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Schimpf, Christian |
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Dunser, M. |
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Thomas, Eric |
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Gecse, Zoltan |
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Tsrunchev, Peter |
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Della Ricca, Giuseppe |
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Cios, Grzegorz |
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Hohlmann, Marcus |
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Dudarev, A. |
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Mascagna, V. |
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Santimaria, Marco |
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Poudyal, Nabin |
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Piozzi, Antonella |
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Mørtsell, Eva Anne |
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Jin, S. |
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Noel, Cédric |
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Fino, Paolo |
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Mailley, Pascal |
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Meyer, Ernst |
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Zhang, Qi |
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Pfattner, Raphael | Brussels |
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Kooi, Bart J. |
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Babuji, Adara |
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Pauporte, Thierry |
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Gallino, Isabella
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Characterization of plastic-metal hybrid composites joined by means of reactive Al/Ni multilayers: evaluation of occurring thermal regime
- 2022Silicon carbide formation in reactive silicon-carbon multilayerscitations
- 2022Solid State Joining of a Cold Rolled Zr-Based Bulk Metallic Glass to a Wrought Aluminum Alloy by Power Ultrasonics
- 2022Effect of composition and thermal history on deformation behavior and cluster connections in model bulk metallic glasses
- 2022Selective laser melting of a Fe-Si-Cr-B-C-based complex-shaped amorphous soft-magnetic electric motor rotor with record dimensions
- 2022On the formation of nanocrystalline aluminides during high pressure torsion of Al/Ni alternating foils and post-processing multilayer reactioncitations
- 2021Phase Transformation and Characterization of 3D Reactive Microstructures in Nanoscale Al/Ni Multilayerscitations
- 2021Influence of Processing Route on the Surface Reactivity of Cu47Ti33Zr11Ni6Sn2Si1 Metallic Glass
- 2018On the Fragility of Bulk Metallic Glass Forming Liquids
- 2015Linking Structure to Fragility in Bulk Metallic Glass-Forming Liquidscitations
- 2015Beta Relaxation and Low Temperature Aging of a Gold Based Bulk Metallic Glass
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article
Influence of Processing Route on the Surface Reactivity of Cu47Ti33Zr11Ni6Sn2Si1 Metallic Glass
Abstract
Recently, laser additive manufacturing (AM) techniques have emerged as a promising alternative for the synthesis of bulk metallic glasses (BMGs) with massively increased freedom in part size and geometry, thus extending their economic applicability of this material class. Nevertheless, porosity, compositional inhomogeneity, and crystallization display themselves to be the emerging challenges for this processing route. The impact of these “defects” on the surface reactivity and susceptibility to corrosion was seldom investigated but is critical for the further development of 3D-printed BMGs. This work compares the surface reactivity of cast and additively manufactured (via laser powder bed fusion—LPBF) Cu47Ti33Zr11Ni6Sn2Si1 metallic glass after 21 days of immersion in a corrosive HCl solution. The cast material presents lower oxygen content, homogeneous chemical distribution of the main elements, and the surface remains unaffected after the corrosion experimentation based on vertical scanning interferometry (VSI) investigation. On the contrary, the LPBF material presents a considerably higher reactivity seen through crack propagations on the surface. It exhibits higher oxygen content, heterogeneous chemical distribution, and presence of defects (porosity and cracks) generated during the manufacturing process.