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Grohsjean, Alexander |
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Falmagne, G. |
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Erice, C. |
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Hernandez, A. M. Vargas |
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Leiton, A. G. Stahl |
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Lipka, K. |
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Pantaleo, F. |
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Torterotot, L. |
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Savina, M. |
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Cerri, O. |
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Jung, A. W. |
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Chiarito, B. |
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Sahin, M. O. |
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Strong, G. |
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Saradhy, R. |
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Joshi, B. M. |
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Kaynak, B. |
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Barrera, C. Baldenegro |
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Longo, Egidio |
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Kolberg, Ted |
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Ferguson, Thomas |
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Leverington, Blake |
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Haase, Fabian |
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Heath, Helen F. |
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Kokkas, Panagiotis |
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Deubener, J.
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Publications (9/9 displayed)
- 2023Hydrogen Permeability of Tectosilicate Glasses for Tank Barrier Liners
- 2022Silver dissolution and precipitation in an Na2O–ZnO–B2O3 metallization paste glasscitations
- 2021Reducing the raw material usage for room temperature infusible and polymerisable thermoplastic CFRPs through reuse of recycled waste matrix materialcitations
- 2020Hydrogen Permeation Through Glasscitations
- 2019Density, elastic constants and indentation hardness of hydrous soda-lime silica glassescitations
- 2018Updated definition of glass-ceramicscitations
- 2016Water, the other network modifier in borate glassescitations
- 2012Hardness and crack behavior of compressed borate glasses
- 2011Crystallization kinetics of LaF3 nanocrystals in an oxyfluoride glasscitations
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article
Hydrogen Permeability of Tectosilicate Glasses for Tank Barrier Liners
Abstract
The permeation of hydrogen gas was studied in meta-aluminous (tectosilicate) glass powders of Li2O×Al2O3×SiO2 (LAS), Na2O×Al2O3×SiO2 (NAS) and MgO×Al2O3×SiO2 (MAS) systems by pressure loading and vacuum extraction in the temperatures range 210–310 °C. With this method, both the solubility S and the diffusivity D were determined, while the permeability was given by the product SD. For all glasses, S was found to decrease with temperature, while D increased. Since the activation energy of diffusion of H2 molecules exceeded that of dissolution, permeation increased slightly with temperature. When extrapolated to standard conditions (25 °C), the permeability of tectosilicate glasses was found to be only 10-22–10-24 mol H2 (m s Pa)-1, which is 8–10 magnitudes lower than most polymers. Thin glass liners of these compositions are expected to be the most effective barrier for tanks of pressurised hydrogen.