People | Locations | Statistics |
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Ferrari, A. |
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Schimpf, Christian |
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Dunser, M. |
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Thomas, Eric |
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Gecse, Zoltan |
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Tsrunchev, Peter |
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Della Ricca, Giuseppe |
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Cios, Grzegorz |
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Hohlmann, Marcus |
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Dudarev, A. |
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Mascagna, V. |
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Santimaria, Marco |
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Poudyal, Nabin |
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Piozzi, Antonella |
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Mørtsell, Eva Anne |
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Jin, S. |
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Noel, Cédric |
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Fino, Paolo |
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Mailley, Pascal |
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Meyer, Ernst |
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Zhang, Qi |
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Pfattner, Raphael | Brussels |
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Kooi, Bart J. |
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Babuji, Adara |
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Pauporte, Thierry |
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Mayrhofer, L.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2019Atomistic insights into lubricated tungsten/diamond sliding contactscitations
- 2018Confined electron and hole states in semiconducting carbon nanotube sub-10 nm artificial quantum dotscitations
- 2016Interfacial insight in multi-junction metal oxide photoanodes for water splitting applicationscitations
- 2016Fluorine-terminated diamond surfaces as dense dipole lattices: The electrostatic origin of polar hydrophobicitycitations
- 2016Integrated strategy toward self-powering and selectivity tuning of semiconductor gas sensorscitations
- 2015Novel approaches towards highly selective self-powered gas sensorscitations
- 2015An old workhorse for new applications: Fe(dpm)(3) as a precursor for low-temperature PECVD of iron(III) oxidecitations
- 2014Highly selective SAM-nanowire hybrid NO2 sensor: Insight into charge transfer dynamics and alignment of frontier molecular orbitalscitations
- 2013Changes in the structural dimensionality of selenidostannates in ionic liquids: Formation, structures, stability, and photoconductivitycitations
- 2011Charge-transfer model for carbonaceous electrodes in polar environmentscitations
Places of action
article
An old workhorse for new applications: Fe(dpm)(3) as a precursor for low-temperature PECVD of iron(III) oxide
Abstract
S.11174-11181 ; An iron(III) beta-diketonate complex, Fe(dpm)(3) (Hdpm = 2,2,6,6-tetramethyl-3,5-heptanedione), has been investigated as a potential precursor for plasma enhanced chemical vapor deposition (PECVD) of iron(III) oxide nanomaterials. Thanks to the combined experimental-theoretical approach, spectroscopic properties, spin state, thermal behavior and fragmentation pathways of Fe(dpm)(3) have been carefully analysed, obtaining an excellent agreement between simulation and experiment. Preliminary PECVD tests evidenced the possibility of obtaining pure and homogeneous Fe2O3 deposits with controlled nano-organization at temperatures as low as 100 degrees C, even on flexible plastic substrates. The present results open up intriguing perspectives for the exploitation of Fe(dpm)(3) as an efficient molecular source for the preparation of nanostructured iron(III) oxides to be used in energetics and gas sensing applications. ; 17 ; Nr.17