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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vej-Hansen, Ulrik Grønbjerg
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2020QuantumATK: an integrated platform of electronic and atomic-scale modelling tools
- 2020QuantumATK: An integrated platform of electronic and atomic-scale modelling toolscitations
- 2017New Platinum Alloy Catalysts for Oxygen Electroreduction Based on Alkaline Earth Metalscitations
- 2017New Platinum Alloy Catalysts for Oxygen Electroreduction Based on Alkaline Earth Metalscitations
- 2016Exploring the Lanthanide Contraction to Tune the Activity and Stability of Pt
- 2016Exploring the Lanthanide Contraction to Tune the Activity and Stability of Pt
- 2016Correlation between diffusion barriers and alloying energy in binary alloyscitations
- 2016Pt x Gd alloy formation on Pt(111): Preparation and structural characterizationcitations
- 2015Controlling the Activity and Stability of Pt-Based Electrocatalysts By Means of the Lanthanide Contraction
- 2015Structure, activity, and stability of platinum alloys as catalysts for the oxygen reduction reaction
- 2015Correlating Structure and Oxygen Reduction Activity on Y/Pt(111) and Gd/Pt(111) Single Crystals
- 2014Understanding the Oxygen Reduction Reaction on a Y/Pt(111) Single Crystal
- 2014Engineering the Activity and Stability of Pt-Alloy Cathode Fuel-Cell Electrocatalysts by Tuning the Pt-Pt Distance
- 2012Understanding the electrocatalysis of oxygen reduction on platinum and its alloyscitations
- 2010Computer simulations of nanoindentation in Mg-Cu and Cu-Zr metallic glassescitations
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document
Exploring the Lanthanide Contraction to Tune the Activity and Stability of Pt
Abstract
The high platinum loadings required to compensate for the slow kinetics of the oxygen reduction reaction (ORR) impede the widespread uptake of polymer electrolyte membrane fuel cells. In order to improve the ORR kinetics and reduce the Pt loading, we can tailor the electronic properties of the Pt surface atoms by means of alloying Pt with other metals. Researchers have intensively studied alloys of Pt with late transition metals such as Ni and Co during the last decades. However, these compounds typically degrade under fuel cell reaction conditions, due to dealloying. In contrast, alloys of Pt and lanthanides present very negative enthalpy of formation [1,2], which should increase their resistance to degradation.