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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Saha, Basudeb
Lancaster University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2022Synthesis of green thermo-responsive amphoteric terpolymer functionalized silica nanocomposite derived from waste vegetable oil triglycerides for enhanced oil recovery (EOR)citations
- 2019Synthesis and characterization of a novel amphoteric terpolymer nanocomposite for enhanced oil recovery applications
- 2019Synthesis and characterization of a novel amphoteric terpolymer nanocomposite for enhanced oil recovery applications
- 2019Systematic multivariate optimisation of butylene carbonate synthesis via CO <inf>2</inf> utilisation using graphene-inorganic nanocomposite catalystscitations
- 2018Greener synthesis of dimethyl carbonate using a novel tin-zirconia/graphene nanocomposite catalystcitations
- 2018A facile and greener synthesis of butylene carbonate via CO2 utilisation using a novel copper–zirconia oxide/graphene catalyst
- 2018Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts
- 2018Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalystcitations
- 2017Greener synthesis of styrene carbonate from CO2 using graphene-inorganic nanocomposite catalysts
- 2017Greener synthesis of 1, 2 butylene carbonate from CO2 using graphene-inorganic nanocomposite catalysis
- 2017Carbon dioxide utilization by graphene based nanocomposite materials as catalysts
Places of action
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document
Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts
Abstract
The synthesis of butylene carbonate (BC) through the reaction of butylene oxide (BO) and carbon dioxide has been investigated using highly efficient graphene-inorganic heterogeneous catalyst, lathana-cerium-zirconia and graphene oxide represented as La– Ce–Zr–GO nanocomposite. The catalysts have been extensively characterised using transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) surface area measurement powder X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) analysis. Response Surface Methodology (RSM) using Box-Behnken Design (BBD) has been applied to optimise the single and interactive effect of four independent reaction variables, i.e. temperature, pressure, catalyst loading and time, on the conversion of BO and BC yield. Two quadratic regression models have been developed representing an empirical relationship between each reaction response and all the independent variables. The predicted models have been validated statistically and experimentally, where the high agreement was observed between predicted and experimental results with approximate relative errors of ±1.5% for both the conversion BO and the yield of BC.