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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lastusaari, Mika
University of Turku
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023CaWO<sub>4</sub>:Yb<sup>3+</sup>,Tm<sup>3+</sup> Crystals and SrAl<sub>2</sub>O<sub>4</sub>:Eu<sup>2+</sup>,Dy<sup>3+</sup> Phosphors in Glass-Based Composites for Green Afterglow after NIR Excitation
- 2022Simultaneously enhanced electrical conductivity and suppressed thermal conductivity for ALD ZnO films via purge-time controlled defectscitations
- 2022Luminescent (Er,Ho)2O3 thin films by ALD to enhance the performance of silicon solar cellscitations
- 2021Luminescent (Er,Ho)2O3 thin films by ALD to enhance the performance of silicon solar cellscitations
- 2021Detection of X‐Ray Doses with Color‐Changing Hackmanites: Mechanism and Applicationcitations
- 2020Series of Near-IR-Absorbing Transition Metal Complexes with Redox Active Ligandscitations
- 2019Up-converting ALD/MLD thin films with Yb3+, Er3+ in amorphous organic frameworkcitations
- 2017Effect of Partial Crystallization on the Structural and Luminescence Properties of Er3+-Doped Phosphate Glassescitations
- 2017Effect of Partial Crystallization on the Structural and Luminescence Properties of Er3+-Doped Phosphate Glassescitations
- 2017Effect of Partial Crystallization on the Structural and Luminescence Properties of Er3$-Doped Phosphate Glassescitations
- 2015In situ hybridization of pulp fibres using Mg-Al layered double hydroxides
- 2007Upconversion Properties of Nanocrystalline ZrO2:Yb3+, Er3+ Phosphorscitations
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article
In situ hybridization of pulp fibres using Mg-Al layered double hydroxides
Abstract
Inorganic Mg2+ and Al3+ containing layered double hydroxide (LDH) particles<br/>were synthesised in situ from aqueous solution onto chemical pulp fibers of pine (Pinus sylvestris). High super saturated (hss) solution with sodium carbonate produced LDH particles with an average diameter of 100–200 nm. Nano-size (70 nm) LDH particles were found from fibers external surface and, to a lesser degree, from the S2 cell wall after synthesis via low super saturated (lss) route. The synthesis via slow urea hydrolysis (Uhyd) yielded micron and clay sized LDH (2–5 µm) and enabled efficient fiber densification via mineralization of S2 fiber wall layer as indicated by TEM and compliance analysis.<br/>The Uhyd method decreased fiber compliance up to 50%. Reduction in the polymerization degree of cellulose was observed with capillary viscometry. Thermogravimetric analysis showed that the hybridization with LDH reduced the exothermic heat, indicating, that this material can be incorporated in flame retardant applications. Fiber charge was assessed by adsorption expermients with methylene blue (MB) and metanil yellow (MY). Synthesis via lss route retained most of the fibres original charge and provided the highest capacity<br/>(10 µmol/g) for anionic MY, indicating cationic character of hybrid fibers. Our results suggested that mineralized fibers can be potentially used in advanced applications such as biocomposites and adsorbent materials