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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Korneychuk, Svetlana
Karlsruhe Institute of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Local Hydrogen Concentration and Distribution in Pd Nanoparticles: An In Situ STEM‐EELS Approach
- 2021Single‐Shot Fabrication of Semiconducting–Superconducting Nanowire Devicescitations
- 2020Shadow-wall lithography of ballistic superconductor-semiconductor quantum devicescitations
- 2018Measurement of the indirect band gap of diamond with EELS in STEM
- 2018Nanostructured nitrogen doped diamond for the detection of toxic metal ions
- 2018Nanostructured nitrogen doped diamond for the detection of toxic metal ions
- 2017On the Origin of Diamond Plates Deposited at Low Temperaturecitations
- 2017Vertically aligned diamond-graphite hybrid nanorod arrays with superior field electron emission propertiescitations
- 2016The effect of molecular structure of organic compound on the direct high-pressure synthesis of boron-doped nanodiamondcitations
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article
Nanostructured nitrogen doped diamond for the detection of toxic metal ions
Abstract
his work demonstrates the applicability of one-dimensional nitrogen-doped diamond nanorods (N-DNRs) for the simultaneous electrochemical (EC) detection of Pb2+ and Cd2+ ions in an electrolyte solution. Well separated voltammetric peaks are observed for Pb2+ and Cd2+ ions using N-DNRs as a working electrode in square wave anodic stripping voltammetry measurements. Moreover, the cyclic voltammetry response of N-DNR electrodes towards the Fe(CN)(6)(/4-)/Fe(CN)(6)(/3-) redox reaction is better as compared to undoped DNR electrodes. This enhancement of EC performance in N-DNR electrodes is accounted by the increased amount of sp(2) bonded nanographitic phases, enhancing the electrical conductivity at the grain boundary (GB) regions. These findings are supported by transmission electron microscopy and electron energy loss spectroscopy studies. Consequently, the GB defect induced N-DNRs exhibit better adsorption of metal ions, which makes such samples promising candidates for next generation EC sensing devices. (C) 2018 Elsevier Ltd. All rights reserved.