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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Weiss-Hortala, Elsa
IMT Mines Albi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2023The mechanisms of calcium-catalyzed graphenization of cellulose and lignin biochars uncoveredcitations
- 2022Calcium as an innovative and effective catalyst for the synthesis of graphene-like materials from cellulosecitations
- 2022Calcium as an innovative and effective catalyst for the synthesis of graphene-like materials from cellulosecitations
- 2021Impact of Atmosphere on Recovered Carbon Fibers From Poly Ether Ether Ketone (PEEK) Based Composites During Thermoconversioncitations
- 2019Physico-chemical properties of carbon fibers recycled by steam-thermolysis of PEEK matrix composites and composite wastes mixture
- 2019Reactivity and deactivation mechanisms of pyrolysis chars from bio-waste during catalytic cracking of tarcitations
- 2019Reactivity and deactivation mechanisms of pyrolysis chars from bio-waste during catalytic cracking of tarcitations
- 2018Recovery of carbon fibres from composite waste by hydrolysis in subcritical water
- 2018Advanced characterization unravels the structure and reactivity of wood-based charscitations
- 2018Advanced characterization unravels the structure and reactivity of wood-based charscitations
- 2017Recovery of carbon fibers from composite waste by solvolysis in subcritical water using a view cell reactor
- 2017IMPACT OF SUBCRITICAL AND SUPERCRITICAL WATER ON BOTH DEPOLYMERIZATION KINETICS OF NYLON 6 AND RECYCLING CARBON FIBERS FROM WASTE COMPOSITE
- 2017Impact of Solvolysis Process on Both Depolymerization Kinetics of Nylon 6 and Recycling Carbon Fibers from Waste Compositecitations
- 2016Impact of subcritical and supercritical water on both depolymerization kinetics of nylon 6 and recycling carbon fibers from waste composite
- 2016Experimental study of self-heating phenomena during torrefaction of spherical wood particles
- 2014Hydrothermal depolymerization of carbon-based composites
Places of action
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conferencepaper
Hydrothermal depolymerization of carbon-based composites
Abstract
The global demand of carbon fiber is increasing, therefore an increasing amount of carbon fiber reinforced polymer waste is produced. Carbon fibers are high added value materials which would be recycled at the composite end of life to offer positive impacts on environment and economic development. Hydrothermal treatments in water or in solvents are also gaining more attention to recycle carbon fibers and valorize polymer matrix into useful materials at the same time. This study focuses on the impact of operating conditions on the depolymerization of the matrix and on the surface quality of the fibers. Carbon fibers reinforced PA6 (thermoplastic polymer, 45 wt. %) are depolymerized in sub and supercritical water (Tc=374°C and Pc=22.1MPa). The experiments were carried out in batch reactors of 5mL at various operating conditions. The whole operating conditions are suitable to remove the polymer from the carbon fibers. A minimum of 39 wt. % of resin is removed in all cases after 30 min treatment while the surface quality of the fibers remains close to their virgin state. The increase of pressure and temperature favors the kinetics, however reaction time plays an important role on the carbon distribution. Indeed, repolymerization reaction (carbonization) is supposed to occur and discussed.